{"id":"W1963657552","doi":"10.1063/1.3276917","title":"X-ray spectroscopy studies on the surface structural characteristics and electronic properties of platinum nanoparticles","year":2009,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Gold and Silver Nanoparticles Synthesis and Applications","field":"Materials Science","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Dalhousie University","keywords":"X-ray photoelectron spectroscopy; X-ray absorption spectroscopy; Platinum; Analytical Chemistry (journal); Valence (chemistry); Chemistry; Nanoparticle; Absorption spectroscopy; Electronic structure; Spectroscopy; Platinum nanoparticles; Binding energy; Physical chemistry; Materials science; Nanotechnology; Computational chemistry; Nuclear magnetic resonance; Atomic physics; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000164736,0.0002453728,0.0002630687,0.000198693,0.0001826492,0.0002145311,0.0002542097,0.0003807832,0.001519376],"category_scores_gemma":[0.0003683173,0.0001749064,0.0002212056,0.0002151512,0.000195365,0.0002509548,0.0001577566,0.0003275384,0.0003018801],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002031207,"about_ca_system_score_gemma":0.00005736068,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004835111,"about_ca_topic_score_gemma":0.0004841439,"domain_scores_codex":[0.9998755,0.00001525813,0.00001112331,0.00003007145,0.00004823208,0.0000197304],"domain_scores_gemma":[0.9998525,0.00005434714,0.00002174739,0.00001308637,0.00004739329,0.00001081865],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005315414,0.00001094613,0.0003456168,0.0000366075,0.000005777561,0.00003396714,0.0000276785,0.0001349828,0.9979091,0.00005156821,0.00002266546,0.001367724],"study_design_scores_gemma":[0.000002718684,0.00008770794,0.002837311,0.000001740655,0.000009411076,0.0000832266,0.0000205831,0.0008338374,0.9956572,0.00002471188,0.0004391476,0.000002408795],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9933895,0.0007363977,0.003854379,0.00006795317,0.00001351912,0.00001672386,0.000146115,0.00004390165,0.001731588],"genre_scores_gemma":[0.9937908,0.0004798236,0.003636085,0.0000484926,0.000007106498,0.00001910767,0.0002165184,0.0000161734,0.001785879],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001519376,"threshold_uncertainty_score":0.005082846,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02458539230325268,"score_gpt":0.2518708552778222,"score_spread":0.2272854629745695,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}