{"id":"W1963889762","doi":"10.1139/v07-142","title":"Synthesis of possible <i>o</i>-thioquinone methide precursors","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Flash vacuum pyrolysis; Pyrolysis; Quinone methide; Sulfur; Organic chemistry; Medicinal chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000101906,0.0003154089,0.000146028,0.0001569437,0.0001246651,0.0001543139,0.0002996558,0.0002182123,0.002164887],"category_scores_gemma":[0.0002050622,0.0001451439,0.0001497336,0.0001706003,0.0001106417,0.0002046532,0.0001555903,0.000312429,0.0005796297],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001275792,"about_ca_system_score_gemma":0.0001761126,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000247002,"about_ca_topic_score_gemma":0.0006522972,"domain_scores_codex":[0.9999433,0.000009395885,0.000004108897,0.00001192525,0.00001600713,0.00001536478],"domain_scores_gemma":[0.9998997,0.00002004236,0.00002392099,0.00001377426,0.00002385536,0.00001859448],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004944999,0.00001201941,0.00008749491,0.0000814274,0.000003528952,0.0001355663,0.00004554657,0.0001530935,0.9964467,0.0003279638,0.00004093384,0.002616236],"study_design_scores_gemma":[0.00001213313,0.000293937,0.0005521475,0.000006622638,0.000007950774,0.0001924167,0.00002432963,0.0003252928,0.9951195,0.00007775277,0.003382342,0.000005704059],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9631603,0.001810007,0.02257081,0.00008073301,0.0000590403,0.0001665889,0.0004941737,0.0001445169,0.01151386],"genre_scores_gemma":[0.9760934,0.001538212,0.01733653,0.00002942722,0.00001016966,0.00006698354,0.0004094402,0.00005314098,0.004462735],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002164887,"threshold_uncertainty_score":0.007242322,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01616819008608342,"score_gpt":0.2142393835719586,"score_spread":0.1980711934858752,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}