{"id":"W1963951456","doi":"10.1021/jp8089159","title":"Volumetric Properties of Solvation in Binary Solvents","year":2009,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Thermodynamic properties of mixtures","field":"Chemical Engineering","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Solvation; Partial molar property; Chemistry; Solvent; Thermodynamics; Work (physics); Aqueous solution; Physical chemistry; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004123539,0.0002699399,0.0003021164,0.0007071772,0.0002046575,0.000495774,0.0003678667,0.0001980657,0.0007187103],"category_scores_gemma":[0.001895013,0.000175261,0.0002415783,0.000490511,0.0009887994,0.0009159697,0.0006129722,0.0002440563,0.0001534193],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003603169,"about_ca_system_score_gemma":0.0002831146,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003804321,"about_ca_topic_score_gemma":0.0002377189,"domain_scores_codex":[0.9997491,0.00003689879,0.00001384238,0.00004840375,0.0001127757,0.00003895435],"domain_scores_gemma":[0.9994639,0.0002959238,0.0001036902,0.00004216984,0.00006684431,0.00002757307],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002171434,0.00007697195,0.005932503,0.0003845052,0.00004661005,0.0003627345,0.0003092403,0.1897034,0.6538759,0.1152916,0.000429958,0.03336933],"study_design_scores_gemma":[0.00001567874,0.000118287,0.005646726,0.00002348006,0.00001756185,0.0003261137,0.00008146813,0.6765202,0.267542,0.04782293,0.001820493,0.00006504565],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7569921,0.001581208,0.2347352,0.0001707415,0.00002345479,0.00003753011,0.0002308637,0.0002205401,0.006008349],"genre_scores_gemma":[0.9948054,0.0004282049,0.004112722,0.0000184851,0.00001233205,0.00002421632,0.00008854606,0.00001853891,0.0004915405],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007187103,"threshold_uncertainty_score":0.00261426,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01030957231492595,"score_gpt":0.2118055848946389,"score_spread":0.2014960125797129,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}