{"id":"W1964015414","doi":"10.1002/chin.200913072","title":"ChemInform Abstract: Efficient Palladium/1,10‐Phenanthroline‐Catalyzed Reductive Carbonylation of Mono‐ and Dinitroarenes to Urethanes in Phosphonium Salt Ionic Liquids.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Carbonylation; Phosphonium; Phenanthroline; Salt (chemistry); Phosphonium salt; Ionic liquid; Palladium; Catalysis; Ionic bonding; Combinatorial chemistry; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002779901,0.000705494,0.0002210157,0.0002938532,0.0002090445,0.0002578077,0.000669376,0.0004002225,0.005191486],"category_scores_gemma":[0.0002488467,0.0002202192,0.0002160643,0.0003437432,0.0002644221,0.0007062767,0.0005169075,0.0008029255,0.002860384],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004531876,"about_ca_system_score_gemma":0.0006729933,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005370519,"about_ca_topic_score_gemma":0.001251698,"domain_scores_codex":[0.9998029,0.00002398986,0.00001551306,0.00003962482,0.00005808784,0.00005995719],"domain_scores_gemma":[0.9999235,0.00001246129,0.00002420271,0.000008769856,0.0000112376,0.0000198759],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003299913,0.0001206445,0.0001282737,0.0007437572,0.00003600423,0.0002478832,0.0001427707,0.0005160487,0.9667246,0.002414825,0.006822621,0.02177263],"study_design_scores_gemma":[0.00001741437,0.0001479872,0.000164031,0.00001126385,0.000009411065,0.00009366077,0.00001015675,0.0003909254,0.9903813,0.00008493384,0.008678868,0.000009907604],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8020989,0.009666258,0.06466481,0.001863162,0.0009529048,0.0004675347,0.004823876,0.003848849,0.1116138],"genre_scores_gemma":[0.9543749,0.004148255,0.01286369,0.000349182,0.00007592977,0.00009842042,0.002115267,0.0003520445,0.02562229],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005191486,"threshold_uncertainty_score":0.01736724,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01068438477787102,"score_gpt":0.2363531827641026,"score_spread":0.2256687979862316,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}