{"id":"W1964167012","doi":"10.1039/b927030b","title":"Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: fluorescence enhancement and C60 sensing","year":2010,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Diastereomer; Fluorescence; Supramolecular chemistry; Ligand (biochemistry); Chemistry; Cage; Crystallography; Stereochemistry; Crystal structure; Receptor; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008007019,0.0001086117,0.0001151809,0.00003033,0.0001253942,0.00003771681,0.0002706994,0.0001070039,0.0000397169],"category_scores_gemma":[0.0000622571,0.00011561,0.00003982757,0.0000749051,0.0001324688,0.0001866629,0.0001580124,0.0002863229,0.000003061528],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002255959,"about_ca_system_score_gemma":0.000009438298,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002697712,"about_ca_topic_score_gemma":0.0000135898,"domain_scores_codex":[0.9992748,0.00003137045,0.0002641503,0.0001594145,0.0001454641,0.0001247568],"domain_scores_gemma":[0.9987204,0.00003958375,0.0001567697,0.0009010149,0.00009772093,0.00008451248],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000005444373,0.0001014459,0.000009457902,0.00004632746,0.00000690838,2.448332e-7,0.0004122706,1.586795e-7,0.9905699,0.00009691583,0.00005405247,0.008696912],"study_design_scores_gemma":[0.0002137369,0.00001528113,0.00001439106,0.000022938,0.00002461295,0.00001960286,0.0001341365,0.01422384,0.9832172,0.00009690063,0.001897323,0.0001200137],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995859,0.0001102635,0.001943044,0.000210202,0.0000230535,0.00007042033,0.00001242247,0.00005378017,0.001717843],"genre_scores_gemma":[0.9815377,0.00006719353,0.01804854,0.00003800325,0.00001870575,0.000009133449,0.0002285492,0.00001316611,0.00003898422],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0161055,"threshold_uncertainty_score":0.471444,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01132664708063465,"score_gpt":0.2483647247892904,"score_spread":0.2370380777086558,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}