{"id":"W1964177709","doi":"10.1016/s0022-328x(00)00390-9","title":"Synthesis and reactivity of subvalent compounds","year":2000,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; University of Toronto; York University","keywords":"Chemistry; Reactivity (psychology); Deuterium; Hydrogen–deuterium exchange; Ring (chemistry); Hydrogen; Organic chemistry; Medicinal chemistry; Computational chemistry; Nuclear physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001432623,0.0001743333,0.000150682,0.0002339865,0.000257244,0.0003826126,0.0003650321,0.0002650372,0.002416345],"category_scores_gemma":[0.0001663096,0.0001219886,0.00008537214,0.0001840287,0.0001540602,0.0002291352,0.0001909404,0.0003626463,0.0004949277],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003502472,"about_ca_system_score_gemma":0.0002034376,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003945162,"about_ca_topic_score_gemma":0.001035502,"domain_scores_codex":[0.9998974,0.00001576296,0.00000935479,0.0000208057,0.00003089118,0.00002591181],"domain_scores_gemma":[0.9999353,0.00001357253,0.00001113441,0.00001299911,0.00001383177,0.0000132289],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001881695,0.00006775933,0.0002696381,0.0001748692,0.00001750747,0.000110435,0.00007768408,0.0006072502,0.9857816,0.003864507,0.0004781965,0.008362354],"study_design_scores_gemma":[0.00001866134,0.0002071423,0.0005461872,0.00001045956,0.00001240229,0.0001084675,0.00002308228,0.0005235932,0.9879885,0.0003061128,0.01024631,0.000009178082],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9729828,0.002925695,0.003919035,0.000183625,0.00009017061,0.00004035126,0.0003989213,0.0001048347,0.01935463],"genre_scores_gemma":[0.9873504,0.001568716,0.002375477,0.00008678976,0.00001574472,0.00002356695,0.000462318,0.00003880068,0.00807822],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002416345,"threshold_uncertainty_score":0.008083463,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008017846557516684,"score_gpt":0.211590070845016,"score_spread":0.2035722242874993,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}