{"id":"W1964235547","doi":"10.1021/ol802085j","title":"Rapid Enantiomeric Excess and Concentration Determination Using Simple Racemic Metal Complexes","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Molecular spectroscopy and chirality","field":"Chemistry","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"National Institute of General Medical Sciences","keywords":"Chemistry; Enantiomer; Metal; Circular dichroism; Enantiomeric excess; Ligand (biochemistry); Stereochemistry; Organic chemistry; Receptor; Enantioselective synthesis; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001177928,0.001152018,0.0009037434,0.0009822156,0.0006421488,0.0008791035,0.00107296,0.0007384279,0.001691214],"category_scores_gemma":[0.001830537,0.0006770816,0.0002634723,0.0006337781,0.0006832171,0.0004114308,0.0004776826,0.001280914,0.001622955],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006015736,"about_ca_system_score_gemma":0.000528822,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008918305,"about_ca_topic_score_gemma":0.001985437,"domain_scores_codex":[0.9980914,0.0003663617,0.0001820193,0.0005715488,0.000604724,0.000183977],"domain_scores_gemma":[0.9988846,0.0002121862,0.0001426375,0.0002848782,0.0003876965,0.00008796019],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004622909,0.00003001093,0.0001875329,0.00002958016,0.000008815121,0.00003138703,0.00002718804,0.00009916446,0.9958563,0.0002382973,0.0001226766,0.003322808],"study_design_scores_gemma":[0.000007570121,0.00004124025,0.0001943634,0.000003508983,0.000005761083,0.00007478171,0.000009279265,0.0005563358,0.9979863,0.00005751473,0.001056251,0.000007032307],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6004832,0.003422725,0.3714429,0.0005152688,0.0002529189,0.001283919,0.003014012,0.00290584,0.01667924],"genre_scores_gemma":[0.7416503,0.002282469,0.242792,0.0003344845,0.00005664659,0.0006891793,0.00201326,0.0003903642,0.009791407],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001691214,"threshold_uncertainty_score":0.00622952,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01855222851620671,"score_gpt":0.2512377243488275,"score_spread":0.2326854958326208,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}