{"id":"W1964235547","doi":"10.1021/ol802085j","title":"Rapid Enantiomeric Excess and Concentration Determination Using Simple Racemic Metal Complexes","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Molecular spectroscopy and chirality","field":"Chemistry","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"National Institute of General Medical Sciences","keywords":"Chemistry; Enantiomer; Metal; Circular dichroism; Enantiomeric excess; Ligand (biochemistry); Stereochemistry; Organic chemistry; Receptor; Enantioselective synthesis; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005295911,0.0001226744,0.0001455012,0.00002057559,0.0001940752,0.00002886353,0.00008117496,0.00004885671,0.0006494303],"category_scores_gemma":[0.00001775521,0.0001246926,0.00003837745,0.0001000197,0.0001108168,0.0001604861,0.00002806865,0.00009927429,0.000005922439],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006865143,"about_ca_system_score_gemma":0.00002928907,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002977592,"about_ca_topic_score_gemma":0.000002997278,"domain_scores_codex":[0.9992382,0.00003083317,0.0001712696,0.0002197852,0.0001480232,0.0001918824],"domain_scores_gemma":[0.9996545,0.00002031741,0.0001027769,0.0001584589,0.00001581235,0.00004808832],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008783775,0.00001592207,0.002152735,0.00002976331,0.00001569917,0.00002381595,0.0002483672,0.000001889049,0.9970619,0.00001915879,0.00005160375,0.0003703827],"study_design_scores_gemma":[0.0004592927,0.000008985034,0.001385937,0.000008547236,0.00003474322,0.0001464876,0.00003301575,0.0009649438,0.9964243,0.00002237162,0.0003505161,0.0001608364],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9937043,0.0001518528,0.005659701,0.0001944464,0.00004659185,0.00004699909,0.000005790853,0.00004952064,0.0001408379],"genre_scores_gemma":[0.9987819,0.00005149682,0.0005120472,0.0004913227,0.00008791798,0.00000216235,0.00004287291,0.00001721771,0.00001307308],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005147654,"threshold_uncertainty_score":0.7110806,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01855222851620671,"score_gpt":0.2512377243488275,"score_spread":0.2326854958326208,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}