{"id":"W1964347708","doi":"10.1002/jms.1677","title":"Structure characterization of lipocyclopeptide antibiotics, aspartocins A, B &amp; C, by ESI‐MSMS and ESI‐nozzle‐skimmer‐MSMS","year":2009,"lang":"en","type":"article","venue":"Journal of Mass Spectrometry","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Women's Health Research Institute","funders":"","keywords":"Chemistry; Moiety; Mass spectrometry; Ion; Mass spectrum; Stereochemistry; Peptide; Electrospray ionization; Chromatography; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001631653,0.0003000464,0.0006447536,0.0001924514,0.00007826048,0.00006857794,0.0003189218,0.0002884953,0.001395259],"category_scores_gemma":[0.0001304362,0.0002651516,0.0002591025,0.0004377404,0.0001236744,0.0002381467,0.0000296608,0.0005988136,0.000003205047],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006603963,"about_ca_system_score_gemma":0.00004767389,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002537916,"about_ca_topic_score_gemma":0.000001209811,"domain_scores_codex":[0.9980152,0.00002316588,0.0008181627,0.0002588331,0.0005353889,0.0003491961],"domain_scores_gemma":[0.998324,0.00006361074,0.0008703098,0.0003034057,0.0001696264,0.0002690005],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000912609,0.0001778111,0.01541865,0.0001539935,0.0001836436,0.00002314502,0.00004556862,0.000002613819,0.9826589,0.0001220766,0.0008232523,0.0002990735],"study_design_scores_gemma":[0.0007102569,0.0001630052,0.01370369,0.0002065935,0.0001995068,0.0002051586,0.00008491427,0.00002622134,0.9817931,0.0009226483,0.001684193,0.000300679],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940642,0.0004518096,0.001662672,0.0004335679,0.00006715969,0.00003682394,0.0001167729,0.00002129403,0.003145681],"genre_scores_gemma":[0.9963187,0.000517396,0.001949053,0.00009759255,0.0004102627,6.051405e-8,0.00005899319,0.00002486219,0.000623078],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002522603,"threshold_uncertainty_score":0.9999801,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004635489871977804,"score_gpt":0.2162619738919499,"score_spread":0.2116264840199721,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}