{"id":"W1964364510","doi":"10.1021/om900584n","title":"Through-Bond versus Through-Space T<sub>1</sub> Energy Transfers in Organometallic Compound−Metalloporphyrin Pigments","year":2009,"lang":"en","type":"article","venue":"Organometallics","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Porphyrin; Tetraphenylporphyrin; Dihedral angle; Chromophore; Crystallography; Acceptor; Photochemistry; Luminescence; Quenching (fluorescence); Stereochemistry; Fluorescence; Molecule; Hydrogen bond; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001244979,0.0002953505,0.0001508496,0.0001750494,0.0002213476,0.0004724834,0.0002937484,0.0003114031,0.001656333],"category_scores_gemma":[0.0002946207,0.0001548909,0.0001092151,0.0001558887,0.0002828209,0.0003340772,0.0004845783,0.0003157285,0.0003597745],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004020534,"about_ca_system_score_gemma":0.0001368388,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002218985,"about_ca_topic_score_gemma":0.0002609596,"domain_scores_codex":[0.9998889,0.00001913799,0.000006085427,0.00002237204,0.0000338496,0.00002969937],"domain_scores_gemma":[0.9998745,0.00003650932,0.00004417948,0.00001601376,0.00001092081,0.00001781751],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000108835,0.0000267458,0.0002528708,0.00005655281,0.000006897761,0.00009638094,0.00005953286,0.0004261941,0.9950559,0.0009370515,0.00004778721,0.002925165],"study_design_scores_gemma":[0.000009016161,0.0001070861,0.001156097,0.000003458142,0.000005666824,0.00008773606,0.00003241523,0.001426297,0.9963546,0.0001377017,0.0006749729,0.000004956929],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975375,0.0001634945,0.001046776,0.00001679915,0.000006470947,0.000008775787,0.0000154563,0.00003957918,0.001165081],"genre_scores_gemma":[0.9983412,0.0001221513,0.0007082269,0.000007629981,0.000001834147,0.00001038101,0.00001631034,0.00001976,0.0007724634],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001656333,"threshold_uncertainty_score":0.005540967,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02081358123300589,"score_gpt":0.2446414226016285,"score_spread":0.2238278413686226,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}