{"id":"W1964390785","doi":"10.1002/ejoc.201301368","title":"A Robust, Well‐Defined Homogeneous Silver(I) Catalyst for Mild Intramolecular Hydroamination of 2‐Ethynylanilines Leading to Indoles","year":2014,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hydroamination; Intramolecular force; Chemistry; Catalysis; Homogeneous; Indole test; Homogeneous catalysis; Combinatorial chemistry; Organic chemistry; Polymer chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0006602054,0.0002547011,0.0004412728,0.000083633,0.00008378601,0.00004099069,0.0005450048,0.00007834814,0.0004374328],"category_scores_gemma":[0.001384122,0.0002607753,0.0002611191,0.000232384,0.00006972654,0.00008111441,0.0001073645,0.0003202872,0.00004229167],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001723603,"about_ca_system_score_gemma":0.0001159613,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002494078,"about_ca_topic_score_gemma":0.000002318856,"domain_scores_codex":[0.9981989,0.000034477,0.0008763624,0.0002765031,0.0003431283,0.0002706525],"domain_scores_gemma":[0.9979673,0.000209596,0.0007520742,0.0004538578,0.0003960975,0.0002210642],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006933114,0.0001119023,0.00006836747,0.0003243845,0.0001272692,0.00003408544,0.0001887163,0.0005124721,0.9949155,0.00000431246,0.001142959,0.002500733],"study_design_scores_gemma":[0.001127059,0.00006938473,0.00004605472,0.0002621704,0.0001962927,0.0006433643,0.0002483425,0.000228231,0.9839122,0.00001985855,0.01299181,0.0002551858],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9693429,0.0002528602,0.01822874,0.0002992878,0.0001287933,0.0000790199,0.00002849376,0.00004235475,0.01159759],"genre_scores_gemma":[0.9949954,0.00001961643,0.002112351,0.00003970634,0.0007814525,0.000001652413,0.00004868607,0.00009811857,0.001902996],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02565256,"threshold_uncertainty_score":0.9999844,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01436774656051656,"score_gpt":0.217460266744703,"score_spread":0.2030925201841864,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}