{"id":"W1964521924","doi":"10.1142/s1088424607000291","title":"The photophysics of metalloporphyrins excited in their Soret and higher energy UV absorption bands","year":2007,"lang":"en","type":"article","venue":"Journal of Porphyrins and Phthalocyanines","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Excited state; Chemistry; Intramolecular force; Relaxation (psychology); Excitation; Atomic orbital; Internal conversion; Intermolecular force; Diamagnetism; Photochemistry; Singlet state; Electron transfer; Chemical physics; Atomic physics; Molecule; Electron","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001137099,0.0003364644,0.0003094908,0.0003981558,0.0001628817,0.0002828236,0.0002362218,0.0002722857,0.001355418],"category_scores_gemma":[0.0001645932,0.0001040599,0.0002155043,0.00026921,0.0001538018,0.0002517128,0.0001877079,0.0002659466,0.0003521552],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002623844,"about_ca_system_score_gemma":0.00009828958,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001371558,"about_ca_topic_score_gemma":0.0001602367,"domain_scores_codex":[0.999945,0.000009668796,0.000002162063,0.00001027542,0.00002507142,0.000007879206],"domain_scores_gemma":[0.9999112,0.00005290005,0.00001216517,0.000003887583,0.00001404483,0.00000584297],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002190226,0.0001146494,0.0009136678,0.006151322,0.00008193803,0.0008090357,0.0001427328,0.004263087,0.7537567,0.008458218,0.003457249,0.2216323],"study_design_scores_gemma":[0.00002423593,0.001558203,0.02094979,0.0006033902,0.0001678885,0.005689334,0.0002575608,0.004325988,0.6658112,0.01189536,0.2886595,0.00005747719],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"review","genre_gemma":"empirical","genre_scores_codex":[0.2704208,0.6889614,0.009337933,0.000546819,0.0003856484,0.00004396205,0.0001213396,0.0001342368,0.03004795],"genre_scores_gemma":[0.4753027,0.4927171,0.00505484,0.0003406763,0.0003010044,0.00007981495,0.000284798,0.00004206325,0.02587694],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.001355418,"threshold_uncertainty_score":0.004534304,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01112840948101918,"score_gpt":0.2320794016758988,"score_spread":0.2209509921948796,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}