{"id":"W1964551161","doi":"10.1021/ol060266w","title":"Total Synthesis of (−)-Xyloketal A","year":2006,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"British Columbia Knowledge Development Fund","keywords":"Chemistry; Boron trifluoride; Hydroxymethyl; Acetal; Total synthesis; Electrophile; Phloroglucinol; Natural product; Bicyclic molecule; Organic chemistry; Stereochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001303053,0.0005907011,0.0003332978,0.0003241329,0.000300032,0.0003310759,0.0003371458,0.000182873,0.003137026],"category_scores_gemma":[0.000116664,0.0001715598,0.0003110277,0.0003327483,0.0001945931,0.0002689601,0.0004500352,0.0004981658,0.001593478],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003147601,"about_ca_system_score_gemma":0.000747026,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007525718,"about_ca_topic_score_gemma":0.001311442,"domain_scores_codex":[0.9998608,0.00001301097,0.00001101679,0.00003336858,0.00003510771,0.00004675547],"domain_scores_gemma":[0.9999173,0.000006614278,0.00001029721,0.00001241801,0.00002067537,0.00003279632],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007890036,0.00003025542,0.00006042271,0.0001344553,0.00001955418,0.0001269325,0.00003702937,0.0002908658,0.9898024,0.0014637,0.0002082538,0.007747146],"study_design_scores_gemma":[0.00002094002,0.0001917074,0.0003524932,0.000007708732,0.00002314538,0.0001961004,0.00001660063,0.0003037667,0.9862804,0.0002472328,0.01234647,0.00001340298],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8786199,0.004117134,0.06824147,0.0001998211,0.0002929914,0.0004580572,0.00384316,0.0007497898,0.04347766],"genre_scores_gemma":[0.9618271,0.003110172,0.01816487,0.00006980024,0.00003001161,0.0001240443,0.00168757,0.0001325524,0.01485376],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003137026,"threshold_uncertainty_score":0.01049441,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004669815426792244,"score_gpt":0.1820802279118016,"score_spread":0.1774104124850094,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}