{"id":"W1964596782","doi":"10.1021/cm050271e","title":"A New Route to Monolithic Methylsilsesquioxanes:  Gelation Behavior of Methyltrimethoxysilane and Morphology of Resulting Methylsilsesquioxanes under One-Step and Two-Step Processing","year":2005,"lang":"en","type":"article","venue":"Chemistry of Materials","topic":"Silicone and Siloxane Chemistry","field":"Materials Science","cited_by":127,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Methyltrimethoxysilane; Materials science; Polymerization; Condensation polymer; Sol-gel; Polymer; Chemical engineering; Porosity; Morphology (biology); Phase (matter); Catalysis; Homogeneous; Condensation; Base (topology); Isoelectric point; Polymer chemistry; Nanotechnology; Organic chemistry; Chemistry; Composite material; Coating","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002065571,0.0005769979,0.0001969188,0.0003029977,0.000171394,0.0003671668,0.0003540183,0.0005777893,0.0008240816],"category_scores_gemma":[0.000187216,0.000419833,0.0002863123,0.0001308612,0.0002773995,0.000460107,0.0002694,0.001162723,0.0004032057],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002817911,"about_ca_system_score_gemma":0.0002924686,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000494249,"about_ca_topic_score_gemma":0.0009420468,"domain_scores_codex":[0.9998498,0.00001398504,0.00001332176,0.0000448439,0.00005107429,0.00002689568],"domain_scores_gemma":[0.9998356,0.00003113278,0.00005050824,0.00002509594,0.0000298708,0.00002770338],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000005476039,0.00000861166,0.00001699577,0.00001265061,0.000002190406,0.00001167846,0.000009407788,0.00001893641,0.9993232,0.00006779825,0.000009769071,0.0005133134],"study_design_scores_gemma":[0.000007736041,0.00009916326,0.0004108073,0.000002007312,0.000003539015,0.00007949064,0.000004238855,0.0003850329,0.9981026,0.00002948953,0.000871079,0.000004834531],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9354644,0.002292556,0.05669387,0.0002402522,0.00008569252,0.0003033177,0.0003879829,0.0006422999,0.003889717],"genre_scores_gemma":[0.9451082,0.001142698,0.04877068,0.0001621008,0.00002276583,0.0001749517,0.0002819183,0.0001302955,0.004206413],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008240816,"threshold_uncertainty_score":0.002756894,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02927255649244958,"score_gpt":0.3026256003633139,"score_spread":0.2733530438708643,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}