{"id":"W1964596782","doi":"10.1021/cm050271e","title":"A New Route to Monolithic Methylsilsesquioxanes:  Gelation Behavior of Methyltrimethoxysilane and Morphology of Resulting Methylsilsesquioxanes under One-Step and Two-Step Processing","year":2005,"lang":"en","type":"article","venue":"Chemistry of Materials","topic":"Silicone and Siloxane Chemistry","field":"Materials Science","cited_by":127,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Methyltrimethoxysilane; Materials science; Polymerization; Condensation polymer; Sol-gel; Polymer; Chemical engineering; Porosity; Morphology (biology); Phase (matter); Catalysis; Homogeneous; Condensation; Base (topology); Isoelectric point; Polymer chemistry; Nanotechnology; Organic chemistry; Chemistry; Composite material; Coating","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001395585,0.0003586349,0.001134702,0.00009930348,0.00007145082,0.00005332795,0.0003283599,0.0003184451,0.0003971944],"category_scores_gemma":[0.0005035155,0.0003579182,0.00007082534,0.0002201756,0.000299078,0.0002455406,0.0002410125,0.0001217144,0.000003747783],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004996159,"about_ca_system_score_gemma":0.0001784192,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007200351,"about_ca_topic_score_gemma":0.000006742791,"domain_scores_codex":[0.9971181,0.000116483,0.001337183,0.0006583415,0.0003736144,0.0003962488],"domain_scores_gemma":[0.9976999,0.0003277007,0.0009724275,0.0005035092,0.0002738939,0.0002225264],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002413381,0.00009159774,0.0003961037,0.001169262,0.00003012226,0.000002720986,0.0005945419,0.00005352935,0.9930325,0.00002187462,0.00002237663,0.004344009],"study_design_scores_gemma":[0.001171474,0.00006532806,0.001357353,0.0003209197,0.0002381394,0.00006520465,0.0005862261,0.00001188696,0.9957376,0.0000945374,0.00003756044,0.0003138204],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970894,0.001475291,0.000535814,0.0001367593,0.0000736264,0.0003200131,0.0001247976,0.0000487887,0.0001954985],"genre_scores_gemma":[0.9357085,0.00004529768,0.06370127,0.00003416822,0.0001862943,0.00002952233,0.00002550588,0.00003568865,0.0002337052],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06316546,"threshold_uncertainty_score":0.9998873,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02927255649244958,"score_gpt":0.3026256003633139,"score_spread":0.2733530438708643,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}