{"id":"W1964637145","doi":"10.1021/es0520767","title":"Atmospheric Chemistry of<i>N</i>-methyl Perfluorobutane Sulfonamidoethanol, C<sub>4</sub>F<sub>9</sub>SO<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>OH:  Kinetics and Mechanism of Reaction with OH","year":2006,"lang":"en","type":"article","venue":"Environmental Science & Technology","topic":"Per- and polyfluoroalkyl substances research","field":"Environmental Science","cited_by":297,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ford Motor Company (Canada); University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Radical; Trifluoroacetic acid; Medicinal chemistry; Sulfonic acid; Reaction mechanism; Methyl group; Nuclear chemistry; Organic chemistry; Alkyl; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001218004,0.0004018888,0.0001024673,0.0001499173,0.0003453933,0.0001974559,0.000205921,0.0003680121,0.001271268],"category_scores_gemma":[0.000133696,0.0001029414,0.0001430315,0.00009811455,0.0001534826,0.0002632152,0.0001350338,0.0002156819,0.0002468577],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005784718,"about_ca_system_score_gemma":0.0002414139,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.006933137,"about_ca_topic_score_gemma":0.004237249,"domain_scores_codex":[0.9999212,0.000006381256,0.000002412957,0.00002333521,0.00003098127,0.00001568978],"domain_scores_gemma":[0.9999571,0.000007634229,0.000009343348,0.000002724263,0.00001666607,0.000006513775],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001047544,0.00001092644,0.005908527,0.00005936205,0.00001109795,0.00006015179,0.00003870994,0.0002247251,0.9893664,0.0001410223,0.0002065389,0.003867873],"study_design_scores_gemma":[0.00001965083,0.0003213862,0.07428205,0.0000126491,0.00002941693,0.0002996046,0.0001492467,0.002066554,0.9155466,0.0002536899,0.0070056,0.00001346026],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9924273,0.001323215,0.001729538,0.0000920028,0.00003718065,0.00002097632,0.0005665224,0.00008313274,0.0037202],"genre_scores_gemma":[0.9958568,0.0006823693,0.001019954,0.0000394313,0.00001357031,0.00001246897,0.0004882971,0.00001883782,0.001868276],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006933137,"threshold_uncertainty_score":0.01378554,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004253537197021937,"score_gpt":0.1945248853503586,"score_spread":0.1902713481533367,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}