{"id":"W1964637145","doi":"10.1021/es0520767","title":"Atmospheric Chemistry of<i>N</i>-methyl Perfluorobutane Sulfonamidoethanol, C<sub>4</sub>F<sub>9</sub>SO<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>OH:  Kinetics and Mechanism of Reaction with OH","year":2006,"lang":"en","type":"article","venue":"Environmental Science & Technology","topic":"Per- and polyfluoroalkyl substances research","field":"Environmental Science","cited_by":297,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ford Motor Company (Canada); University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Radical; Trifluoroacetic acid; Medicinal chemistry; Sulfonic acid; Reaction mechanism; Methyl group; Nuclear chemistry; Organic chemistry; Alkyl; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.002220548,0.00251649,0.002350773,0.000598737,0.001870528,0.0003345789,0.003710516,0.002233831,0.0001685132],"category_scores_gemma":[0.0002682577,0.002541659,0.0006486721,0.005632499,0.0155653,0.002189897,0.00301552,0.002986281,0.0006695586],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.003658245,"about_ca_system_score_gemma":0.0004260949,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002741293,"about_ca_topic_score_gemma":0.0007837321,"domain_scores_codex":[0.9821835,0.0004571827,0.002678327,0.004910703,0.005059529,0.004710821],"domain_scores_gemma":[0.9928468,0.000402928,0.001947613,0.003293338,0.0001385605,0.001370713],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00037327,0.001389272,0.006508124,0.0001556215,0.0001183303,0.0002365056,0.0003492029,0.0009061022,0.863056,0.0001612492,0.0002089987,0.1265373],"study_design_scores_gemma":[0.002581896,0.001763584,0.02032925,0.0002687442,0.0002748609,0.0009098196,0.0009936399,0.001701296,0.9659607,0.001664162,0.0009487584,0.002603219],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.989693,0.003620506,0.001260835,0.0006115481,0.0005800778,0.002295627,0.000437512,0.0006361705,0.0008646975],"genre_scores_gemma":[0.986864,0.01019352,0.001287426,0.0002295374,0.0002886293,0.0004778046,0.0002408064,0.000364534,0.00005374537],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1239341,"threshold_uncertainty_score":0.9994289,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004253537197021937,"score_gpt":0.1945248853503586,"score_spread":0.1902713481533367,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}