{"id":"W1964706374","doi":"10.1021/ic301324u","title":"Formation, Spectroscopic Characterization, and Solution Stability of an [Fe<sub>4</sub>S<sub>4</sub>]<sup>2+</sup> Cluster Derived from β-Cyclodextrin Dithiolate","year":2012,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metalloenzymes and iron-sulfur proteins","field":"Energy","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"National Institute of General Medical Sciences; Alberta Glycomics Centre; National Institutes of Health; University of Calgary; Harvard University","keywords":"Chemistry; Denticity; Cluster (spacecraft); Crystallography; Intramolecular force; Redox; Ligand (biochemistry); Aqueous solution; Stereochemistry; Circular dichroism; Cyclodextrin; Cubane; Inorganic chemistry; Crystal structure; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001648592,0.0002036703,0.0001739693,0.0001350863,0.0001517058,0.0002439626,0.0002197597,0.0003405754,0.0007252998],"category_scores_gemma":[0.0002591827,0.0001040838,0.0001021506,0.0001067012,0.0002242192,0.0001734763,0.0001260376,0.0002833156,0.0001649777],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002574823,"about_ca_system_score_gemma":0.0001220153,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005642475,"about_ca_topic_score_gemma":0.0005986029,"domain_scores_codex":[0.9999082,0.00001560498,0.000006766926,0.00002322818,0.00003128768,0.00001492309],"domain_scores_gemma":[0.9998468,0.00002644226,0.0000399606,0.00001312352,0.00005081866,0.00002286118],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004026831,0.000007081474,0.0001737132,0.00001762326,0.000003097652,0.0000112925,0.00001214047,0.00004896722,0.9991001,0.0000349413,0.000018047,0.0005327144],"study_design_scores_gemma":[0.000002734014,0.00008701711,0.001419648,0.00000125967,0.000005247163,0.00006775613,0.00001432938,0.0003852513,0.9972958,0.00001747922,0.0007003273,0.000003232566],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9947156,0.0004696013,0.003661633,0.00005742369,0.00001194396,0.00002006463,0.0001764385,0.00006320637,0.0008239908],"genre_scores_gemma":[0.9940723,0.0002193759,0.003997789,0.00003794709,0.000006517347,0.0000228021,0.0003324757,0.00001942533,0.001291363],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007252998,"threshold_uncertainty_score":0.002426386,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009948722235423823,"score_gpt":0.2013262379406418,"score_spread":0.191377515705218,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}