{"id":"W1964937539","doi":"10.1002/1521-3765(20010417)7:8<1679::aid-chem16790>3.0.co;2-5","title":"A Computational Study of Ethylene C−H Bond Activation by [Cp*Ir(PR3)]","year":2001,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Prince Edward Island","funders":"Engineering and Physical Sciences Research Council; European Commission","keywords":"Ethylene; Bond; Chemistry; Business; Organic chemistry; Catalysis; Finance","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004093404,0.0002246267,0.0002952915,0.00003989243,0.0001983519,0.00009564619,0.0004349706,0.00003831696,0.01738902],"category_scores_gemma":[0.00009667608,0.0002176853,0.0001564609,0.0002219925,0.00006181229,0.0001224669,0.0001031187,0.0003897398,0.0000288164],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007784546,"about_ca_system_score_gemma":0.0000473681,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004270376,"about_ca_topic_score_gemma":2.15268e-7,"domain_scores_codex":[0.9982685,0.00006493652,0.0006328404,0.0002994876,0.0004941868,0.0002400624],"domain_scores_gemma":[0.9987524,0.0000824743,0.0004881702,0.0003340284,0.0001588479,0.0001840654],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007739432,0.001260516,0.001449692,0.00006082673,0.0002823613,0.00009020586,0.0006286239,0.000312243,0.9723847,0.000001426429,0.002979411,0.02047259],"study_design_scores_gemma":[0.01168776,0.0003724516,0.01278642,0.0004853117,0.0007779484,0.002376226,0.01771336,0.003977476,0.7375005,0.0002986555,0.2099161,0.002107787],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9677746,0.0001348939,0.000553378,0.0001497175,0.00001803668,0.00003196923,0.00001825057,0.00003647836,0.0312827],"genre_scores_gemma":[0.9953961,0.00003336294,0.0001907853,0.00002542286,0.0003116344,0.000002060088,0.00005988816,0.00004742896,0.00393329],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2348842,"threshold_uncertainty_score":0.9835092,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01630182821969079,"score_gpt":0.2258190305373586,"score_spread":0.2095172023176678,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}