{"id":"W1965359815","doi":"10.1139/v10-071","title":"Is the oxygen “side-on”, or “end-on” and fluctional, in peroxyl radicals with magnetically equivalent oxygen atoms?","year":2010,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; National Institute for Nanotechnology","funders":"","keywords":"Chemistry; Oxygen; Tin; Radical; Oxygen atom; Hyperfine structure; Density functional theory; Group (periodic table); Functional group; Crystallography; Computational chemistry; Atomic physics; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002721419,0.0002371086,0.000293924,0.00006109198,0.0001533815,0.0001167852,0.000482743,0.0002188508,0.009180397],"category_scores_gemma":[0.0002505326,0.0001469541,0.0001001332,0.0001156782,0.0005602321,0.00006717024,0.00001943038,0.001089178,0.00001341429],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009460012,"about_ca_system_score_gemma":0.0012307,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002632015,"about_ca_topic_score_gemma":0.001642348,"domain_scores_codex":[0.9984174,0.00001380405,0.0004405728,0.0002589945,0.0004121225,0.0004570408],"domain_scores_gemma":[0.9982276,0.0001639929,0.0001824081,0.0003515807,0.00009918812,0.0009752404],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000899386,0.0003195272,0.01901711,0.0005814502,0.0004074535,0.00408597,0.0009570133,0.00004147648,0.9179289,0.0008936924,0.03950067,0.01536729],"study_design_scores_gemma":[0.006932087,0.0005457933,0.05398392,0.002039868,0.0001770327,0.01116444,0.001333499,0.0002396611,0.5680945,0.00247691,0.3515167,0.001495632],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9785888,0.0003725893,0.000002084224,0.008674186,0.00008803837,0.00004035787,0.00006186335,0.000006235998,0.01216588],"genre_scores_gemma":[0.9953441,0.00008784411,0.0001490316,0.001112128,0.0006089199,0.00000430612,0.000002992335,0.00003218928,0.002658508],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3498345,"threshold_uncertainty_score":0.9917253,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01262896685461886,"score_gpt":0.2294354320500045,"score_spread":0.2168064651953857,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}