{"id":"W1965384868","doi":"10.1039/c3dt33021d","title":"Synthesis and reactivity of nickel-hydride amino-bis-phosphinimine complexes","year":2013,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Hydride; Chemistry; Reactivity (psychology); Nickel; Cationic polymerization; Bromobenzene; Medicinal chemistry; Ethylene; Polymer chemistry; Stereochemistry; Organic chemistry; Metal; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0000846825,0.000205359,0.0004201312,0.00009293808,0.0001544459,0.00004048826,0.0001799692,0.00009358101,0.04472471],"category_scores_gemma":[0.00004184169,0.0001968685,0.00018364,0.0001889642,0.0001896922,0.0002380914,0.0000139187,0.00015466,0.00004779534],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003319116,"about_ca_system_score_gemma":0.00002763928,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001650787,"about_ca_topic_score_gemma":0.0001643183,"domain_scores_codex":[0.9988478,0.00002121333,0.0003597259,0.0003339434,0.0002011421,0.0002362161],"domain_scores_gemma":[0.9987582,0.0004160136,0.000134508,0.0004969583,0.00006071977,0.0001335949],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001255353,0.0003145063,0.000428086,0.000162235,0.0001970181,0.00000100112,0.0001862453,0.000007615536,0.8649749,0.0001240327,0.00007561648,0.1335163],"study_design_scores_gemma":[0.0002288753,0.00001683702,0.01164299,0.00004554144,0.0003234994,0.00001790016,0.0005873533,0.0004336056,0.9700965,0.0001596844,0.01614052,0.0003066327],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9863477,0.0002639148,0.002162512,0.0004621935,0.00003650814,0.00008537534,0.0002077249,0.00008723949,0.01034681],"genre_scores_gemma":[0.9962396,0.0001822951,0.0004287445,0.00001680026,0.00003012751,0.00008371256,0.00001849568,0.00002849923,0.002971713],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1332096,"threshold_uncertainty_score":0.9561486,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01521015820468032,"score_gpt":0.2196357064528233,"score_spread":0.204425548248143,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}