{"id":"W1965388308","doi":"10.1039/c3dt50314c","title":"Comparative properties of coordinated H2 and H2S at a ruthenium(ii) centre","year":2013,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Adduct; Deprotonation; Chemistry; Ruthenium; Differential scanning calorimetry; Medicinal chemistry; Calorimetry; Solid-state; Osmium; Enthalpy; Physical chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001794552,0.0003327318,0.0003881255,0.0002311478,0.0001541802,0.0003730062,0.0005518253,0.0003087558,0.002151292],"category_scores_gemma":[0.0003259385,0.0002089482,0.0001563803,0.0002605909,0.0004213576,0.000220636,0.0002027061,0.0002512496,0.0003732128],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005027805,"about_ca_system_score_gemma":0.0001617122,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001717712,"about_ca_topic_score_gemma":0.001719224,"domain_scores_codex":[0.999765,0.00003495002,0.00001174096,0.00005859254,0.00008052757,0.00004909574],"domain_scores_gemma":[0.9998481,0.00003547547,0.00002718899,0.00001082667,0.00004006693,0.00003827562],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008173098,0.00002751461,0.0009227387,0.0001359914,0.00005381743,0.0001177479,0.00006915734,0.001458129,0.9933693,0.0002318696,0.0001222455,0.002674342],"study_design_scores_gemma":[0.00003318669,0.00045712,0.004841514,0.000004956107,0.00001964097,0.000112416,0.00006304933,0.002791719,0.9907747,0.00006063429,0.0008215,0.0000195491],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980412,0.0004250617,0.0004482423,0.00001747571,0.000005772696,0.000005154059,0.0001937155,0.00005201564,0.0008112534],"genre_scores_gemma":[0.9989126,0.0001326881,0.0001934975,0.00000906233,0.000003527322,0.000006013208,0.0002477588,0.0000161099,0.0004786446],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002151292,"threshold_uncertainty_score":0.007196724,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02162356574402107,"score_gpt":0.2249147944868558,"score_spread":0.2032912287428347,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}