{"id":"W1965390347","doi":"10.1021/ol802185x","title":"Aromatic <i>ortho</i>-Benzylation Reveals an Unexpected Reductant","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Aromaticity; Combinatorial chemistry; Medicinal chemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000679107,0.0001989977,0.0001338393,0.00007272349,0.000100932,0.0002059387,0.0003076254,0.0002088281,0.001334175],"category_scores_gemma":[0.00009201898,0.00009584917,0.0000964936,0.00008801726,0.0001521913,0.0001734641,0.0002177663,0.0003140344,0.0006147516],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001495451,"about_ca_system_score_gemma":0.00008631121,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000173616,"about_ca_topic_score_gemma":0.0003505517,"domain_scores_codex":[0.9999409,0.000007193416,0.000003071753,0.00001564467,0.00001226903,0.00002096345],"domain_scores_gemma":[0.9999684,0.000005071235,0.000009246796,0.00000714116,0.000004501541,0.000005527831],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004122021,0.000006022118,0.00009046192,0.00004268434,0.000002551981,0.0001413682,0.00002267502,0.00004738846,0.9957838,0.0005691344,0.0001529753,0.003099751],"study_design_scores_gemma":[0.000005590292,0.00005585067,0.0002806301,0.000001968114,0.000003878428,0.000168379,0.000008414806,0.0002167305,0.9955663,0.0001079268,0.00358193,0.000002366715],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.960912,0.001615644,0.01533717,0.0004574013,0.00008027585,0.00002682616,0.0004240057,0.0003821272,0.02076447],"genre_scores_gemma":[0.9932619,0.0005926109,0.002649981,0.00007673896,0.00001412817,0.000009637176,0.0002121787,0.00005449377,0.003128367],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001334175,"threshold_uncertainty_score":0.004463196,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01233296133678378,"score_gpt":0.214113588705208,"score_spread":0.2017806273684242,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}