{"id":"W1965688529","doi":"10.1021/jo302194n","title":"Mild Double Allylboration Reactions of Nitriles and Acid Anhydrides Using Potassium Allyltrifluoroborate","year":2012,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Advanced Synthetic Organic Chemistry","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Boron trifluoride; Chemoselectivity; Potassium; Reagent; Electrophile; Organic chemistry; Boron; Medicinal chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006165152,0.0002570323,0.0003919665,0.00002673413,0.0001509609,0.00002490479,0.0003753277,0.0002083875,0.001524641],"category_scores_gemma":[0.0002695096,0.0002024613,0.00009902209,0.0002292564,0.0002271844,0.0003570795,0.0001200277,0.0005550675,0.000002817339],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001818465,"about_ca_system_score_gemma":0.0002124092,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009190246,"about_ca_topic_score_gemma":0.000001163528,"domain_scores_codex":[0.9982871,0.00002326978,0.0008229935,0.0001381758,0.0003926044,0.0003358759],"domain_scores_gemma":[0.9976558,0.0001805282,0.001208142,0.0004666716,0.0002835402,0.0002053317],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001514419,0.0001162675,0.0007524243,0.0002468332,0.0001139346,0.000002464826,0.0003682753,0.00002827156,0.9979705,0.00000463504,0.00008149735,0.000163404],"study_design_scores_gemma":[0.0008880687,0.000008776762,0.00004960899,0.0001659938,0.0002811918,0.001209354,0.001476088,0.0000321414,0.9949284,0.000100144,0.0006647438,0.0001954544],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9939783,0.003072251,0.0008809054,0.0002115631,0.0001028029,0.00003821291,0.00001662802,0.00002473485,0.001674568],"genre_scores_gemma":[0.9966071,0.000463319,0.001833656,0.00001415762,0.0007009773,7.313828e-7,0.000005769954,0.00005101064,0.0003232703],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003042116,"threshold_uncertainty_score":0.9993881,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02286371637930104,"score_gpt":0.258985467342723,"score_spread":0.236121750963422,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}