{"id":"W1966144922","doi":"10.1021/om0401307","title":"Reactivity of Terminal Electrophilic Phosphinidene Complexes:  Synthesis of the First Rhenium Phosphinidene, [Re(CO)<sub>5</sub>(η<sup>1</sup>-PN<i><sup>i</sup></i>Pr<sub>2</sub>)][AlCl<sub>4</sub>], and Novel Reactions with Azobenzene","year":2005,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences; University of Ottawa","funders":"","keywords":"Phosphinidene; Chemistry; Rhenium; Electrophile; Reactivity (psychology); Phosphine; Medicinal chemistry; Stereochemistry; Crystallography; Inorganic chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.001136701,0.001855369,0.00287796,0.0006912361,0.00105102,0.0002957071,0.002016943,0.0007904387,0.001074774],"category_scores_gemma":[0.000875696,0.00161258,0.001267452,0.002743132,0.001327154,0.001097043,0.0008442653,0.001405892,0.0001109798],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007046227,"about_ca_system_score_gemma":0.0005548468,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002451095,"about_ca_topic_score_gemma":0.0006013282,"domain_scores_codex":[0.9909746,0.0001901848,0.002642654,0.002332739,0.002057647,0.001802193],"domain_scores_gemma":[0.9912295,0.001667786,0.002173417,0.003616265,0.0006198393,0.000693149],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004137989,0.002331938,0.001752223,0.0007655238,0.001542713,0.00002144827,0.0008219521,0.000910893,0.9661595,0.0003172687,0.0002006665,0.02476204],"study_design_scores_gemma":[0.001612943,0.0002039666,0.008404101,0.0005092206,0.002084436,0.0004021979,0.0007357722,0.00194333,0.9764604,0.0001688167,0.005773704,0.001701139],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9937629,0.001056636,0.0002566976,0.001099259,0.00006930219,0.0007271473,0.000873873,0.0002969115,0.001857244],"genre_scores_gemma":[0.9953922,0.002394408,0.0004484971,0.0002056716,0.0005346842,0.0002145686,0.0001620274,0.0004675632,0.0001803838],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0230609,"threshold_uncertainty_score":0.9998384,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0107874743006022,"score_gpt":0.2047468407631551,"score_spread":0.1939593664625529,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}