{"id":"W1966359324","doi":"10.1021/ic010242f","title":"Syntheses, Vibrational Spectra, and Theoretical Studies of the Adamantanoid Sn<sub>4</sub>Ch<sub>10</sub><sup>4</sup><sup>-</sup> (Ch = Se, Te) Anions:  X-ray Crystal Structures of [18-Crown-6-K]<sub>4</sub>[Sn<sub>4</sub>Se<sub>10</sub>]·5en and [18-Crown-6-K]<sub>4</sub>[Sn<sub>4</sub>Te<sub>10</sub>]·3en·2THF","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Crystal Structures and Properties","field":"Materials Science","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; X-ray; Crystallography; Spectral line; Crystal structure; X-ray crystallography; Crystal (programming language); Inorganic compound; Diffraction; Nuclear physics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001133328,0.0002345606,0.0001978057,0.0001167899,0.0002466245,0.0001471194,0.0003714147,0.0001421731,0.002101026],"category_scores_gemma":[0.000192478,0.0001175548,0.000110604,0.0001591979,0.0001854445,0.0001512723,0.0001484497,0.0002970451,0.0003658253],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002361302,"about_ca_system_score_gemma":0.0002332317,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008837538,"about_ca_topic_score_gemma":0.001315033,"domain_scores_codex":[0.9999268,0.000007442316,0.000005374099,0.00001504914,0.00003559365,0.000009654798],"domain_scores_gemma":[0.9999274,0.00001000055,0.00002301247,0.000008101885,0.00002177398,0.00000969963],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001262349,0.00001083656,0.0005242209,0.00008812937,0.000005829655,0.00009015944,0.00009687983,0.0005455653,0.9944533,0.0003845684,0.00006646,0.003607809],"study_design_scores_gemma":[0.00001449917,0.0001677574,0.001531487,0.000005278562,0.00000713061,0.0001460001,0.00009908321,0.001295846,0.9918742,0.0000972056,0.004751993,0.000009631178],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948531,0.0006016843,0.002938032,0.00003141857,0.00001105703,0.00001378923,0.0002184776,0.00002511688,0.001307437],"genre_scores_gemma":[0.9865006,0.0009238929,0.008777623,0.00001831834,0.000008133259,0.00003018341,0.0005924494,0.00002966181,0.003119195],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002101026,"threshold_uncertainty_score":0.007028639,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01597473217016269,"score_gpt":0.2344500763592069,"score_spread":0.2184753441890442,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}