{"id":"W1966382797","doi":"10.1021/ma2006206","title":"Synthesis and Photovoltaic Properties of New Metalloporphyrin-Containing Polyplatinyne Polymers","year":2011,"lang":"en","type":"article","venue":"Macromolecules","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":127,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Thiophene; Photochemistry; Porphyrin; Chromophore; Polymer solar cell; Materials science; Density functional theory; Chemistry; Time-dependent density functional theory; Polymer; Zinc; Polymer chemistry; Organic chemistry; Computational chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008921031,0.0002016901,0.0001517149,0.0001219555,0.00009659413,0.0002799624,0.0001767097,0.0001830104,0.0006671243],"category_scores_gemma":[0.0001702512,0.0001251531,0.0001130706,0.0001993674,0.00009453759,0.000241579,0.0001358928,0.0002900165,0.0001408008],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002455619,"about_ca_system_score_gemma":0.0001017245,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002789824,"about_ca_topic_score_gemma":0.0006676908,"domain_scores_codex":[0.9999446,0.000005236701,0.000005477129,0.00001538788,0.00001802794,0.00001134611],"domain_scores_gemma":[0.9999309,0.0000155854,0.00002185819,0.000007724857,0.000007841965,0.00001612592],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003140802,0.00001548515,0.00009508918,0.00005365616,0.000005260348,0.00005860633,0.00001731939,0.0003282193,0.9967582,0.0001611463,0.00001968223,0.00245599],"study_design_scores_gemma":[0.00001055867,0.00019586,0.001916829,0.000004054054,0.00001151883,0.0001361295,0.000007508451,0.001007337,0.9954377,0.0000282384,0.00123913,0.000005133569],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965131,0.0007629422,0.001529753,0.00003066966,0.00000763092,0.00001867802,0.0001011958,0.00002834471,0.001007901],"genre_scores_gemma":[0.9947849,0.0007554457,0.003145713,0.00001523557,0.000003429702,0.00002120576,0.0001162388,0.00001353984,0.001144198],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006671243,"threshold_uncertainty_score":0.002231777,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03661288992703714,"score_gpt":0.2198906498169287,"score_spread":0.1832777598898916,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}