{"id":"W1966667860","doi":"10.1021/om050844x","title":"Syntheses and Reactivities of New PC<sub>s</sub><sub>p3</sub>P Pincer Complexes of Nickel","year":2005,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":87,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Pincer movement; Cationic polymerization; Acetonitrile; Nickel; Acrylonitrile; Medicinal chemistry; Hydride; Halide; Nuclear magnetic resonance spectroscopy; Inert; Benzene; Inorganic chemistry; Stereochemistry; Polymer chemistry; Organic chemistry; Hydrogen; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001326376,0.0005471564,0.0002737473,0.0002933161,0.0003222466,0.0004940458,0.0005920708,0.0002950975,0.002681786],"category_scores_gemma":[0.0003330539,0.0003319292,0.0002355806,0.0002769785,0.0002846379,0.000387208,0.0004520695,0.000519812,0.0007246223],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006762881,"about_ca_system_score_gemma":0.0002893923,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001043526,"about_ca_topic_score_gemma":0.001857477,"domain_scores_codex":[0.999827,0.00001967188,0.00001899493,0.00003627714,0.00006042595,0.00003770963],"domain_scores_gemma":[0.9998891,0.00001661448,0.00002224784,0.00002332441,0.00002152923,0.00002705083],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002629537,0.00004820105,0.0002345464,0.0002736222,0.00003277145,0.0001552355,0.0001599907,0.000715006,0.9917542,0.001055307,0.0002755208,0.005032701],"study_design_scores_gemma":[0.00001206614,0.0001005988,0.0003142707,0.000003580888,0.00001083465,0.00007206296,0.0000151327,0.0003546705,0.9966727,0.00004597743,0.002390388,0.000007714909],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.977193,0.001269248,0.005180441,0.00009459037,0.00004373295,0.0001922165,0.0004616368,0.0003311218,0.01523406],"genre_scores_gemma":[0.988085,0.0009987215,0.004373404,0.00004499995,0.0000133035,0.0001220143,0.0005664062,0.0001152137,0.005680995],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002681786,"threshold_uncertainty_score":0.008971512,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02059777717316944,"score_gpt":0.2201740309513663,"score_spread":0.1995762537781969,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}