{"id":"W1966695053","doi":"10.1016/j.tet.2010.11.085","title":"Preparation of trifluoroethyl- and phenyl-protected sulfates using sulfuryl imidazolium salts","year":2010,"lang":"en","type":"article","venue":"Tetrahedron","topic":"Organic and Inorganic Chemical Reactions","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada; Suez University; Ministry of Higher Education","keywords":"Chemistry; Yield (engineering); Aryl; Sulfonyl; Medicinal chemistry; Sulfation; Sulfuryl chloride; Sulfonium; Organic chemistry; Salt (chemistry); Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004836014,0.0005006729,0.0004654308,0.0002856457,0.000209362,0.0001967594,0.0004766451,0.0002811205,0.001179032],"category_scores_gemma":[0.0003034507,0.0002486643,0.0003282152,0.0002918805,0.0002007735,0.0002792152,0.0002189609,0.0004292502,0.000774033],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002760779,"about_ca_system_score_gemma":0.0004162397,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004614578,"about_ca_topic_score_gemma":0.0009179225,"domain_scores_codex":[0.9998148,0.00002585135,0.00002534793,0.00002264887,0.00005612117,0.00005519732],"domain_scores_gemma":[0.9998349,0.00002075581,0.00003687782,0.00003535004,0.00003913341,0.00003309915],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002397831,0.00003869563,0.0002049249,0.00008790482,0.00001313093,0.0001694851,0.00009403993,0.0002794228,0.990869,0.0009457864,0.0002996594,0.006758128],"study_design_scores_gemma":[0.00001963964,0.0002435135,0.0002633596,0.00000296669,0.000007208641,0.00005449498,0.00001098011,0.0002942809,0.9969995,0.00006572949,0.002032697,0.000005602425],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9673849,0.001179176,0.02176759,0.0002343601,0.0001683083,0.0001127715,0.0006066214,0.000490865,0.008055449],"genre_scores_gemma":[0.9769536,0.001139123,0.01469467,0.00007699184,0.00004277226,0.00006544964,0.0007950164,0.00009087494,0.006141654],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001179032,"threshold_uncertainty_score":0.003944278,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01209206543166467,"score_gpt":0.279131006506411,"score_spread":0.2670389410747463,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}