{"id":"W1966699451","doi":"10.1021/ol0261635","title":"First Enantioselective Total Synthesis of (−)-Tejedine","year":2002,"lang":"en","type":"article","venue":"Organic Letters","topic":"Botanical Research and Chemistry","field":"Agricultural and Biological Sciences","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Enantioselective synthesis; Chemistry; Total synthesis; Combinatorial chemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001782198,0.0007128185,0.0005363117,0.0002785364,0.000282008,0.0003919192,0.0005263127,0.0003655529,0.002696821],"category_scores_gemma":[0.0001802843,0.0001768881,0.000353046,0.0002438775,0.0002100046,0.0002643908,0.0004069842,0.0006247804,0.001258711],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002541314,"about_ca_system_score_gemma":0.0004376015,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006962867,"about_ca_topic_score_gemma":0.001116872,"domain_scores_codex":[0.9998556,0.00001903612,0.00001428652,0.00003292918,0.0000220894,0.00005602276],"domain_scores_gemma":[0.999934,0.000009197061,0.000009951214,0.000009733672,0.00001651568,0.00002063984],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001944203,0.0000617615,0.0001308384,0.0003603927,0.00004641764,0.0007766607,0.0001651451,0.0008409735,0.9748434,0.00212146,0.0005966396,0.01986198],"study_design_scores_gemma":[0.00005224215,0.0009284212,0.0007813495,0.0000286704,0.00006757129,0.000932399,0.00005215971,0.0006556809,0.9643431,0.0004400688,0.03168525,0.00003314018],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.813556,0.008970784,0.1043808,0.0003382703,0.0007634713,0.0006032379,0.003679147,0.0007945343,0.06691379],"genre_scores_gemma":[0.9429072,0.005746394,0.03167179,0.0001535123,0.00004776689,0.0001233719,0.001585124,0.0001257072,0.01763913],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002696821,"threshold_uncertainty_score":0.009021759,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01189267911801256,"score_gpt":0.1859664136369022,"score_spread":0.1740737345188897,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}