{"id":"W1966951553","doi":"10.1021/ac034011x","title":"Scanning Electrochemical Microscopy. 46. Shielding Effects on Reversible and Quasireversible Reactions","year":2003,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"McMaster University","keywords":"Scanning electrochemical microscopy; Ultramicroelectrode; Chemistry; Electromagnetic shielding; Diffusion; Kinetics; Substrate (aquarium); Electrochemistry; Electrode; Microscopy; Analytical Chemistry (journal); Scanning probe microscopy; Microscope; Nanotechnology; Optics; Cyclic voltammetry; Physical chemistry; Composite material; Materials science; Thermodynamics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001270408,0.0002836392,0.0003407193,0.00003701339,0.0002625883,0.00007172806,0.0001933889,0.0002752221,0.0006598748],"category_scores_gemma":[0.0004145554,0.0002846418,0.0001884489,0.0004091387,0.0001167489,0.00006855725,0.00004491752,0.0006548646,0.00005256],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001547545,"about_ca_system_score_gemma":0.00005955844,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001007388,"about_ca_topic_score_gemma":5.643661e-7,"domain_scores_codex":[0.9982339,0.00001352117,0.0003209205,0.0006455536,0.0002483303,0.0005377731],"domain_scores_gemma":[0.9986989,0.0004194087,0.00006938385,0.0004333421,0.00004792336,0.0003309805],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001565663,0.0001099307,0.0007227747,0.0002143761,0.00009255166,0.000004287515,0.000009855926,0.000001683253,0.995671,0.001816731,0.00122028,0.0001208644],"study_design_scores_gemma":[0.0003228441,0.0000141927,0.000009886824,0.0001176206,0.0001645055,0.00002355973,0.00005416086,0.0003989149,0.9783707,0.00112381,0.01909211,0.0003076726],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8818504,0.0002762164,0.0004474568,0.000461798,0.000009830698,0.00004692862,0.000003614067,0.0001203998,0.1167834],"genre_scores_gemma":[0.9912471,0.00009579681,0.0007249929,0.0002314924,0.0001426271,0.00002738658,0.00004016589,0.0000298675,0.007460637],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1093967,"threshold_uncertainty_score":0.9999606,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007559802875858229,"score_gpt":0.2511156220199678,"score_spread":0.2435558191441096,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}