{"id":"W1967237480","doi":"10.1002/chem.201100891","title":"Bond Stretching and Redox Behavior in Coinage Metal Complexes of the Dichalcogenide Dianions [(SPh<sub>2</sub>P)<sub>2</sub>CEEC(PPh<sub>2</sub>S)<sub>2</sub>]<sup>2−</sup> (E=S, Se): Diradical Character of the Dinuclear Copper(I) Complex (E=S)","year":2011,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Teknologiateollisuuden 100-Vuotisjuhlasäätiö; University of Lethbridge","keywords":"Chemistry; Ligand (biochemistry); Redox; Isomerization; Metathesis; Crystallography; Stereochemistry; Reactivity (psychology); Diselenide; Metal; Medicinal chemistry; Diradical; Diphenyl diselenide; Monomer; Polymerization; Inorganic chemistry; Singlet state; Selenium","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001088638,0.0002633478,0.0001634705,0.0001470725,0.0001484299,0.0002585861,0.0003904724,0.0003518503,0.001944924],"category_scores_gemma":[0.0002873613,0.0001593675,0.00008459263,0.0002372687,0.0002784071,0.0001912999,0.0001535409,0.000385227,0.000196123],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003774324,"about_ca_system_score_gemma":0.0001238486,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001417136,"about_ca_topic_score_gemma":0.001958441,"domain_scores_codex":[0.9998636,0.00001578678,0.00000751191,0.00003365907,0.00004962161,0.00002984268],"domain_scores_gemma":[0.9998962,0.00002119898,0.00002737725,0.000008749417,0.00002727428,0.00001918047],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002122919,0.00001975939,0.0004450683,0.00004940792,0.0000125937,0.00005267914,0.00009811077,0.0001355672,0.9972236,0.0001588978,0.00007047601,0.001521556],"study_design_scores_gemma":[0.0000118559,0.0002404579,0.004985012,0.000005908781,0.00001167193,0.00009879613,0.0000899574,0.001538908,0.9920677,0.00005071684,0.0008889431,0.00001002879],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984373,0.0003030228,0.0003344532,0.00001957721,0.000007705981,0.000005845993,0.00008431724,0.00002966703,0.0007780929],"genre_scores_gemma":[0.9987864,0.0001446933,0.0002794263,0.00001127559,0.00000263654,0.000007219744,0.0001150613,0.000008351854,0.0006449943],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001944924,"threshold_uncertainty_score":0.006506443,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0242440878088227,"score_gpt":0.2089585507481897,"score_spread":0.184714462939367,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}