{"id":"W1967300015","doi":"10.1016/j.chroma.2005.11.111","title":"Interpreting the effects of temperature and solvent composition on separation of amino-acid racemates by chiral ligand-exchange chromatography","year":2005,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":false,"ca_institutions":"Canada's Michael Smith Genome Sciences Centre; University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Pfizer","keywords":"Chemistry; Chromatography; Solvent; Ligand (biochemistry); Organic chemistry; Biochemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002892282,0.0005844696,0.0005469014,0.0004117604,0.0004238623,0.001842074,0.0005360916,0.00059877,0.001094349],"category_scores_gemma":[0.006896358,0.0004484699,0.0003440406,0.0004139072,0.0007933895,0.0008335881,0.0003516206,0.0007941418,0.0004901972],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004834991,"about_ca_system_score_gemma":0.0005534759,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001375254,"about_ca_topic_score_gemma":0.00186166,"domain_scores_codex":[0.9989845,0.0004271026,0.00006612777,0.0001350378,0.0002558561,0.0001313961],"domain_scores_gemma":[0.9967523,0.002196716,0.0003207399,0.000202292,0.0004173717,0.0001106556],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001486649,0.0000527826,0.001748455,0.0000767603,0.00004496606,0.0001414222,0.00005437082,0.001319808,0.9880557,0.0001569845,0.0001467654,0.006715264],"study_design_scores_gemma":[0.00002244591,0.00008621327,0.001676992,0.000004201468,0.00005095691,0.00008685059,0.00002764135,0.004285616,0.9932774,0.000102467,0.0003660538,0.00001313558],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9704315,0.002382517,0.02429733,0.0003130903,0.0001458455,0.00005963569,0.0002473753,0.00036819,0.001754435],"genre_scores_gemma":[0.9860253,0.0012363,0.01104783,0.0003014864,0.0000507208,0.00003269707,0.0002387154,0.0002957039,0.0007712216],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002892282,"threshold_uncertainty_score":0.01529604,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003153042502498353,"score_gpt":0.2289091780365829,"score_spread":0.2257561355340846,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}