{"id":"W1967335626","doi":"10.1002/(sici)1521-3757(20000303)112:5<988::aid-ange988>3.0.co;2-a","title":"Formation of the Azadisulfite Dianion [O2S(μ-NPh)SO2]2− by Twelvefold Insertion of SO2 into the Mg−N(Ph) Bonds of [(thf)MgNPh]6","year":2000,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Killam Trusts","keywords":"Chemistry; Dimer; Cycloaddition; Stereochemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001382079,0.0002819873,0.0001621211,0.00009075046,0.0001465421,0.0002036845,0.0002342638,0.0001689807,0.001538211],"category_scores_gemma":[0.0001150831,0.0001601199,0.0001354763,0.00009014413,0.0002060208,0.0001615446,0.0002277867,0.0001629738,0.000279933],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002596623,"about_ca_system_score_gemma":0.0003251254,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006140182,"about_ca_topic_score_gemma":0.001160293,"domain_scores_codex":[0.9999255,0.00001045737,0.000004555343,0.00001976071,0.00001992039,0.00001981542],"domain_scores_gemma":[0.9999453,0.000004597515,0.00001106973,0.000009208021,0.000007249832,0.00002259911],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001419731,0.00001192433,0.0001624025,0.00003099374,0.000006166259,0.00004116322,0.00004236544,0.0001250731,0.9981915,0.0002438611,0.00005226726,0.000950263],"study_design_scores_gemma":[0.00003648821,0.0001895964,0.0008472501,0.00000141369,0.000008028363,0.00006114339,0.00001813919,0.0005215296,0.996411,0.00006316959,0.001835726,0.000006482962],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976366,0.00007419583,0.0008624409,0.00002411657,0.00001101449,0.00001641819,0.00007704066,0.00004736285,0.001250794],"genre_scores_gemma":[0.9958967,0.00007571051,0.001425026,0.00001175713,0.000002546122,0.00001130935,0.0001951631,0.00001883272,0.002363015],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001538211,"threshold_uncertainty_score":0.005145848,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00714837869972316,"score_gpt":0.194877954014077,"score_spread":0.1877295753143538,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}