{"id":"W1967335626","doi":"10.1002/(sici)1521-3757(20000303)112:5<988::aid-ange988>3.0.co;2-a","title":"Formation of the Azadisulfite Dianion [O2S(μ-NPh)SO2]2− by Twelvefold Insertion of SO2 into the Mg−N(Ph) Bonds of [(thf)MgNPh]6","year":2000,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Killam Trusts","keywords":"Chemistry; Dimer; Cycloaddition; Stereochemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001899339,0.0001879363,0.0002925477,0.00003628473,0.000100292,0.0000207797,0.0003863262,0.0001463193,0.001628891],"category_scores_gemma":[0.00004577768,0.0001262451,0.0001729655,0.0003070884,0.0001380751,0.0002589675,0.00006572064,0.0001261586,0.000007142474],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006351242,"about_ca_system_score_gemma":0.00003565507,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001106724,"about_ca_topic_score_gemma":0.00002237219,"domain_scores_codex":[0.9986364,0.00002896256,0.0006053882,0.0001912,0.0003599852,0.0001780775],"domain_scores_gemma":[0.9987079,0.00007900817,0.000497373,0.0005690388,0.0001050442,0.00004167001],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005110456,0.0001284202,0.0008679583,0.0002351936,0.00003603834,1.110166e-7,0.001462804,0.000004370066,0.9892576,0.00003584422,0.0007723657,0.007148231],"study_design_scores_gemma":[0.0003276197,0.00002256815,0.002162805,0.0001385151,0.00007235109,0.000002551236,0.0001959718,0.00007653744,0.9811828,0.0001839497,0.01550453,0.0001297547],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9913722,0.000393064,0.00002577096,0.0007208062,0.00004375594,0.0001085171,0.00007080388,0.00002475138,0.007240308],"genre_scores_gemma":[0.9977512,0.0005063846,0.00001891028,0.00006581245,0.00008521816,0.00001676344,0.0001668004,0.00002543686,0.001363408],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01473217,"threshold_uncertainty_score":0.9992837,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00714837869972316,"score_gpt":0.194877954014077,"score_spread":0.1877295753143538,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}