{"id":"W1967349336","doi":"10.1021/ol802299d","title":"Copper-Catalyzed Tandem Oxidation−Olefination Process","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Racemization; Catalysis; Tandem; Copper; Compatibility (geochemistry); Combinatorial chemistry; Functional group; Reaction conditions; Oxidation process; Organic chemistry; Chemical engineering","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006386513,0.0002316298,0.0001969377,0.00004660895,0.000296777,0.00003029912,0.0002938219,0.0001270561,0.005305185],"category_scores_gemma":[0.0001905427,0.0002497934,0.00006893167,0.0003519593,0.0001375537,0.0002103641,0.00004628927,0.0002761627,0.0005460121],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003338546,"about_ca_system_score_gemma":0.0001362894,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001002363,"about_ca_topic_score_gemma":0.000005030813,"domain_scores_codex":[0.9986199,0.00001139833,0.0002845258,0.0004198338,0.0003589063,0.0003054273],"domain_scores_gemma":[0.9991156,0.00006423613,0.0001705041,0.0004358329,0.0001009836,0.0001127875],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000004034553,0.00007580998,0.005337974,0.0000356784,0.00004035996,0.0000199892,0.0003653976,0.000003447337,0.98887,0.00001163487,0.005134506,0.0001012085],"study_design_scores_gemma":[0.0006809604,0.000002901981,0.00122869,0.00002033936,0.00002998311,0.0002073639,0.0002221475,0.00003180673,0.9953949,0.0000169861,0.00187305,0.0002908687],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9909855,0.00002282722,0.0003358595,0.003684755,0.00008466651,0.00006483621,0.00001182381,0.0003158521,0.004493881],"genre_scores_gemma":[0.9979653,0.00001646324,0.0001420525,0.0004870503,0.0002821084,0.00002182274,0.0001995988,0.00006086504,0.0008247696],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006979771,"threshold_uncertainty_score":0.9999954,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01375144054199312,"score_gpt":0.2310013790034157,"score_spread":0.2172499384614226,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}