{"id":"W1967478647","doi":"10.1021/jp0486494","title":"In Situ XPS Studies of Perovskite Oxide Surfaces under Electrochemical Polarization","year":2004,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":93,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"X-ray photoelectron spectroscopy; Oxide; Redox; Electrochemistry; Perovskite (structure); Stoichiometry; Polarization (electrochemistry); Materials science; Oxygen; Inorganic chemistry; Chemistry; Electrode; Analytical Chemistry (journal); Chemical engineering; Crystallography; Physical chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001770207,0.0003513122,0.0002654241,0.0001675786,0.0002611973,0.0002538805,0.0003912823,0.0003951523,0.001799957],"category_scores_gemma":[0.0002551898,0.0001877539,0.0001994437,0.0002624734,0.0001890111,0.0002616642,0.0002076321,0.0005279608,0.0002186292],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001769608,"about_ca_system_score_gemma":0.00009702229,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007177448,"about_ca_topic_score_gemma":0.000735591,"domain_scores_codex":[0.9998653,0.00001448241,0.000007337551,0.00003284883,0.00004867872,0.00003131436],"domain_scores_gemma":[0.999902,0.00003020417,0.00001414165,0.000007658237,0.00003489469,0.00001106664],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002526134,0.00000581008,0.0001119808,0.0000244152,0.000003474366,0.0000238461,0.00003566676,0.00003324405,0.9989359,0.00002236682,0.00001786657,0.0007602242],"study_design_scores_gemma":[0.000003871532,0.00006792473,0.002040295,0.000001998804,0.000008297235,0.00009790307,0.00007991736,0.0005250419,0.9963651,0.00004921763,0.0007557975,0.000004546127],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9939181,0.0004599846,0.00350775,0.00009149015,0.000023356,0.00001275033,0.0003202586,0.00005689526,0.001609498],"genre_scores_gemma":[0.9926152,0.0006581832,0.0038688,0.00005786957,0.0000185885,0.00001693455,0.000398941,0.00002344703,0.002341939],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001799957,"threshold_uncertainty_score":0.0060215,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01096064928164571,"score_gpt":0.2625650982938434,"score_spread":0.2516044490121978,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}