{"id":"W1968172445","doi":"10.1016/s1472-7862(01)00010-7","title":"Structural Type and Thermal Stability of Tris (5-acetyl-3-thienyl) Methane Inclusion Compounds: a Combined 13C CP/MAS NMR, Powder X-Ray Diffraction and Differential Scanning Calorimetric Study","year":2001,"lang":"en","type":"article","venue":"Journal of Supramolecular Chemistry","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":false,"ca_institutions":"Carleton University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Differential scanning calorimetry; Crystallography; Magic angle spinning; Halogen; Molecule; Thermal stability; Powder diffraction; Methylene; Nuclear magnetic resonance spectroscopy; Stereochemistry; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008259997,0.0001109378,0.0001148873,0.0001701501,0.000143579,0.0001498337,0.0001446426,0.0001318501,0.001247728],"category_scores_gemma":[0.0001899422,0.0001164049,0.00007810857,0.0001706497,0.0001755541,0.0001557936,0.00008952921,0.0001665071,0.0001704606],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000179421,"about_ca_system_score_gemma":0.0001283737,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001086558,"about_ca_topic_score_gemma":0.001178712,"domain_scores_codex":[0.9999441,0.000006378981,0.000004957685,0.00001147696,0.00001375987,0.00001938618],"domain_scores_gemma":[0.9998969,0.00002471616,0.00002625309,0.000007201309,0.00002646427,0.0000184885],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001687871,0.000005724922,0.0003164941,0.00001934161,0.000003202206,0.00002614015,0.00003638487,0.00008392133,0.9985381,0.00007649078,0.00001983679,0.0007055918],"study_design_scores_gemma":[0.000003833778,0.0001186998,0.005063181,0.000002690478,0.00001045391,0.00009152373,0.00002906944,0.0005702396,0.9936865,0.00001895955,0.0003995057,0.00000540673],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9989297,0.0002889019,0.0003012639,0.00001133243,0.000002247045,0.000002057996,0.0001139322,0.000008251989,0.0003422538],"genre_scores_gemma":[0.9988486,0.0001184561,0.0002182532,0.000004643161,0.000001304672,0.000003880246,0.0002349626,0.000005324536,0.0005645851],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001247728,"threshold_uncertainty_score":0.004174113,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0140817728418768,"score_gpt":0.2586732102682979,"score_spread":0.2445914374264211,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}