{"id":"W1968299376","doi":"10.1021/ic0349454","title":"Outer Sphere Perturbation of Delocalized Mixed-Valence Complexes","year":2004,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University; University of Ottawa","funders":"","keywords":"Chemistry; Comproportionation; Ruthenium; Superexchange; Delocalized electron; Crystallography; Bridging ligand; Valence (chemistry); Acceptor; Photochemistry; Crystal structure; Physical chemistry; Electrochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001069866,0.0004247672,0.0003377799,0.0002420523,0.0003800305,0.0006099287,0.0004310063,0.0003377947,0.004837548],"category_scores_gemma":[0.0003670625,0.0002083768,0.00009535261,0.0001229708,0.0003752502,0.0002774056,0.0006548361,0.000481264,0.0003950378],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005018614,"about_ca_system_score_gemma":0.0001364937,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004862586,"about_ca_topic_score_gemma":0.0003986706,"domain_scores_codex":[0.9998726,0.00002022285,0.000003622567,0.00002682436,0.00004175623,0.00003512621],"domain_scores_gemma":[0.9999005,0.00002464695,0.00001452543,0.00001346157,0.00001818926,0.00002858305],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005019812,0.00007723707,0.0006179269,0.0001200023,0.00003099689,0.0004085732,0.0002519007,0.006784335,0.9630901,0.01822167,0.0006598009,0.009235608],"study_design_scores_gemma":[0.0001215348,0.0004741146,0.004375027,0.00001491633,0.00003328151,0.0007829198,0.0002876009,0.1163608,0.8608893,0.00989954,0.006706172,0.00005495704],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.987571,0.0001654627,0.004055322,0.00007971687,0.00002318424,0.000009669554,0.00003513342,0.0002036875,0.007856814],"genre_scores_gemma":[0.9983747,0.00004510777,0.0005578159,0.00002742813,0.000003465768,0.000005181354,0.00003378106,0.00002984548,0.0009226611],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004837548,"threshold_uncertainty_score":0.0161832,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02332352255662578,"score_gpt":0.2438949531040477,"score_spread":0.220571430547422,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}