{"id":"W1968307821","doi":"10.1002/chin.200941209","title":"ChemInform Abstract: Concise Total Synthesis of (.+‐.)‐Aspidospermidine via an Oxidative Hosomi—Sakurai Process.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Alkaloids: synthesis and pharmacology","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"","keywords":"Chemistry; Process (computing); Combinatorial chemistry; Nanotechnology; Computer science; Programming language","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008214156,0.000595278,0.0008932456,0.0001818395,0.00024843,0.00002704538,0.000705124,0.0007840518,0.0150542],"category_scores_gemma":[0.0003019724,0.0005523516,0.0002809661,0.000372504,0.0004745045,0.0007675308,0.00007684117,0.0009081819,0.0002276823],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001616781,"about_ca_system_score_gemma":0.0002443814,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001716204,"about_ca_topic_score_gemma":0.000003188855,"domain_scores_codex":[0.9971226,0.000002634423,0.00110876,0.000510559,0.0003613935,0.0008939851],"domain_scores_gemma":[0.997307,0.0005842468,0.0007068522,0.0004420501,0.0003652697,0.0005945744],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001014204,0.0008445188,0.0002138293,0.0001969625,0.0002540316,0.00002878741,0.002408761,0.0000117921,0.267977,0.000288643,0.009807521,0.7169539],"study_design_scores_gemma":[0.001371133,0.0003621373,0.003759554,0.00004196071,0.0002942733,0.00008746539,0.0005405905,0.0002520995,0.9763342,0.0003387031,0.0159846,0.0006333462],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5375565,0.0002965738,0.000001078738,0.0004534927,0.0004301763,0.0006188967,0.0001278641,0.0001721724,0.4603432],"genre_scores_gemma":[0.9932844,0.0001944894,0.00004214455,0.001628555,0.0004796577,0.0001157498,0.00009841836,0.00004214073,0.004114469],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.7163206,"threshold_uncertainty_score":0.9996928,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05625368013757095,"score_gpt":0.3886215408341238,"score_spread":0.3323678606965528,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}