{"id":"W1968317318","doi":"10.1021/ol701496b","title":"Strain-Release Electrophilic Activation via <i>E</i>-Cycloalkenones","year":2007,"lang":"en","type":"article","venue":"Organic Letters","topic":"Inorganic and Organometallic Chemistry","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Electrophile; Adduct; Strain (injury); Conjugated system; Double bond; Nitrogen; Photochemistry; Carbonyl group; Medicinal chemistry; Organic chemistry; Catalysis; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001190177,0.0003157914,0.00008994595,0.0001161583,0.0001254419,0.000175813,0.0001770711,0.0001698178,0.00261539],"category_scores_gemma":[0.0001783597,0.00009300472,0.0001444269,0.00007912046,0.0001810916,0.0002405839,0.0001454376,0.0002534095,0.0003947297],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001033684,"about_ca_system_score_gemma":0.00007607991,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000187298,"about_ca_topic_score_gemma":0.0004039276,"domain_scores_codex":[0.9999193,0.00001474512,0.000004937528,0.00001783479,0.00001243754,0.00003078433],"domain_scores_gemma":[0.999907,0.00003014883,0.00002725123,0.00001292562,0.00000943293,0.00001318578],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000134236,0.00001392615,0.0001512221,0.00005057584,0.000005556775,0.00009804373,0.000037201,0.0001224613,0.9966467,0.0003036044,0.00005779749,0.002378662],"study_design_scores_gemma":[0.000006053096,0.00007124911,0.0004955146,0.000002291029,0.000003308842,0.00008763288,0.00001549591,0.0001141548,0.9984179,0.00003362384,0.0007495538,0.000003190427],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9907585,0.0006214282,0.003666329,0.00006552623,0.00002383344,0.00002023296,0.0001322848,0.00005995915,0.004651948],"genre_scores_gemma":[0.9973468,0.0002464032,0.00074573,0.00001883212,0.000005490467,0.000008596956,0.0000831287,0.00001240183,0.001532798],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00261539,"threshold_uncertainty_score":0.008749366,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004644715901374085,"score_gpt":0.1927259392645869,"score_spread":0.1880812233632129,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}