{"id":"W1968394918","doi":"10.1016/s0009-2614(02)01905-x","title":"Generation of the elusive methyl dioxophosphorane molecule, CH3P(O)2, by delayed dissociation of selected precursors","year":2003,"lang":"en","type":"article","venue":"Chemical Physics Letters","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":12,"is_retracted":false,"has_abstract":false,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Dissociation (chemistry); Ionization; Molecule; Tautomer; Enol; Ab initio; Mass spectrometry; Methanethiol; Ab initio quantum chemistry methods; Photochemistry; Computational chemistry; Analytical Chemistry (journal); Medicinal chemistry; Physical chemistry; Ion; Organic chemistry; Sulfur","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004218012,0.0002158634,0.0003300596,0.000009090624,0.00006643488,0.000006871747,0.0002034664,0.00004410871,0.00001182989],"category_scores_gemma":[0.00004585976,0.0001822168,0.0001882714,0.0004806377,0.0001901945,0.00009775775,0.00005798556,0.0002136538,0.00000163293],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006664424,"about_ca_system_score_gemma":0.00002712298,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002561411,"about_ca_topic_score_gemma":1.164575e-7,"domain_scores_codex":[0.9988111,0.00005370448,0.0003305227,0.0002667985,0.0002913214,0.0002465199],"domain_scores_gemma":[0.9989954,0.0001049593,0.0003896602,0.0002739205,0.0001918212,0.00004427878],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001022236,0.0001588266,0.0007356875,0.00001293004,0.0001767542,3.203206e-8,0.0002514628,0.0004019232,0.9916874,0.002763309,0.003495379,0.0003060513],"study_design_scores_gemma":[0.0003948413,0.000010469,0.00004342123,0.00001315378,0.00007778774,3.733866e-8,0.00003736076,0.00008784331,0.9893385,0.009764673,0.0000547885,0.0001771425],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9819009,0.00006108364,0.01675013,0.0001887793,0.00007845256,0.0002257648,0.00009968069,0.00001421153,0.0006809917],"genre_scores_gemma":[0.9989236,0.000002278551,0.0005858373,0.0001093529,0.0001550827,0.00003148646,0.0001419531,0.00002884317,0.00002155145],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01702271,"threshold_uncertainty_score":0.7430586,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00833759716180113,"score_gpt":0.2263492777508698,"score_spread":0.2180116805890687,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}