{"id":"W1968470608","doi":"10.1002/adsc.200900051","title":"Asymmetric Hydrogenation of α,β‐Unsaturated Ester‐ Phosphonates","year":2009,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Rhodium; Asymmetric hydrogenation; Yield (engineering); Catalysis; Organic chemistry; Enantioselective synthesis; Combinatorial chemistry; Optically active","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001453202,0.0004780411,0.0001891108,0.0001513085,0.0001028302,0.000212591,0.0003580017,0.000309294,0.003979255],"category_scores_gemma":[0.0001430082,0.000174758,0.0001497391,0.0001170291,0.0002041282,0.000431989,0.0002686257,0.0004801352,0.0009210768],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002654274,"about_ca_system_score_gemma":0.0002755808,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009618935,"about_ca_topic_score_gemma":0.001190533,"domain_scores_codex":[0.999903,0.000009135942,0.000005733802,0.00001693449,0.00002822196,0.00003701494],"domain_scores_gemma":[0.9999518,0.000009440605,0.00001303007,0.000006484171,0.000007324015,0.0000119463],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001169284,0.00001371833,0.00003457534,0.00006451921,0.000005206136,0.0001843884,0.0000229415,0.0002457346,0.9941869,0.0009199938,0.0002205243,0.003984548],"study_design_scores_gemma":[0.0000143626,0.00005416928,0.0001410312,0.000002190607,0.000002916404,0.0001019837,0.000007590462,0.000418491,0.9973391,0.00005658088,0.001856973,0.000004577095],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9350029,0.001407086,0.01747251,0.0003756391,0.0002434491,0.0001068617,0.0006350867,0.00036543,0.04439111],"genre_scores_gemma":[0.9851863,0.0009551538,0.004548127,0.00007531385,0.00002485416,0.000024132,0.0002542921,0.00005519219,0.008876663],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003979255,"threshold_uncertainty_score":0.01331198,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006037982053652117,"score_gpt":0.2277748406994188,"score_spread":0.2217368586457667,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}