{"id":"W1968470608","doi":"10.1002/adsc.200900051","title":"Asymmetric Hydrogenation of α,β‐Unsaturated Ester‐ Phosphonates","year":2009,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Rhodium; Asymmetric hydrogenation; Yield (engineering); Catalysis; Organic chemistry; Enantioselective synthesis; Combinatorial chemistry; Optically active","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002676075,0.0003604238,0.0006708216,0.0008412672,0.0001402132,0.00003706527,0.0005274301,0.0002045207,0.0007383372],"category_scores_gemma":[0.001246113,0.0003498999,0.0004627097,0.003883275,0.00007481055,0.0004211759,0.00004381235,0.0001745883,0.0001129689],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001751756,"about_ca_system_score_gemma":0.00005401689,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004765642,"about_ca_topic_score_gemma":0.000008512187,"domain_scores_codex":[0.9974192,0.00003688415,0.0008014783,0.000614013,0.0007168367,0.0004115243],"domain_scores_gemma":[0.9975946,0.0004987472,0.0005796267,0.0008433007,0.0003103581,0.0001733971],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008321907,0.0003494136,0.000385688,0.00003952063,0.0003565206,0.000009653113,0.0001258327,0.0006530518,0.2489057,0.000200459,0.0000797508,0.7488112],"study_design_scores_gemma":[0.0003724477,0.00002176483,0.000699868,0.00003799414,0.000423904,0.000007867222,0.0002078077,0.001641026,0.9927784,0.0002715302,0.003148863,0.0003885146],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.942257,0.004656143,0.00188048,0.0004922758,0.00008802173,0.0001770708,0.0001073001,0.0004441778,0.0498975],"genre_scores_gemma":[0.9967115,0.0003852507,0.001463125,0.000106486,0.00003750806,0.0000427338,0.0002902349,0.00003580675,0.0009273757],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.7484227,"threshold_uncertainty_score":0.9998953,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006037982053652117,"score_gpt":0.2277748406994188,"score_spread":0.2217368586457667,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}