{"id":"W1968532751","doi":"10.1021/jp0493576","title":"Atmospheric Chemistry of 4:2 Fluorotelomer Alcohol (CF<sub>3</sub>(CF<sub>2</sub>)<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>OH):  Products and Mechanism of Cl Atom Initiated Oxidation","year":2004,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Per- and polyfluoroalkyl substances research","field":"Environmental Science","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Diluent; Alcohol; Yield (engineering); Medicinal chemistry; Molecule; Torr; Oxygen; Reaction mechanism; Fourier transform infrared spectroscopy; Organic chemistry; Nuclear chemistry; Catalysis; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.001807861,0.001455539,0.001895528,0.00007171413,0.000629528,0.0001821717,0.001985437,0.0007751733,0.0001078611],"category_scores_gemma":[0.000482356,0.001268553,0.0007944416,0.002170494,0.001913275,0.001355671,0.0009141998,0.002542815,0.0001906336],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001103894,"about_ca_system_score_gemma":0.0005957767,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005252918,"about_ca_topic_score_gemma":0.00002428794,"domain_scores_codex":[0.9904329,0.0004586919,0.002264695,0.001475792,0.003410189,0.001957706],"domain_scores_gemma":[0.9938793,0.0004874989,0.002271013,0.001631643,0.0005790679,0.001151519],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009938598,0.001461681,0.0001529814,0.0007080399,0.0004198098,0.0001192828,0.001165002,0.002141603,0.9700077,0.00003010286,0.0004357532,0.0223642],"study_design_scores_gemma":[0.003407506,0.0004681684,0.001787319,0.0006336313,0.0004349425,0.0004218355,0.0004000253,0.001171057,0.9877421,0.00213431,0.0001319781,0.001267074],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954209,0.001479856,0.0005032796,0.000530392,0.0001572111,0.0009130113,0.0001559412,0.000115768,0.0007235879],"genre_scores_gemma":[0.995703,0.002481128,0.0001993127,0.0001671421,0.00102757,0.00007241761,0.0001105574,0.0002157988,0.0000231105],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02109713,"threshold_uncertainty_score":0.9998194,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01418548239765707,"score_gpt":0.241509949949692,"score_spread":0.2273244675520349,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}