{"id":"W1968572241","doi":"10.1021/ol0615937","title":"A Retro-Diels−Alder Reaction to Uncover Maleimide-Modified Surfaces on Monolayer-Protected Nanoparticles for Reversible Covalent Assembly","year":2006,"lang":"en","type":"article","venue":"Organic Letters","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Maleimide; Chemistry; Covalent bond; Monolayer; Diels–Alder reaction; Nanoparticle; Polymer chemistry; Nanotechnology; Organic chemistry; Catalysis; Biochemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002288806,0.0005180963,0.0001709106,0.0002689438,0.0001607787,0.0001741736,0.0004649526,0.0003085754,0.001870948],"category_scores_gemma":[0.0001524319,0.0002719476,0.0002035498,0.0001367936,0.0001994113,0.0002849172,0.0001934795,0.0004754422,0.0007113679],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002864149,"about_ca_system_score_gemma":0.0001789251,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002434136,"about_ca_topic_score_gemma":0.0006531934,"domain_scores_codex":[0.9998778,0.00001511396,0.000006043315,0.00002999155,0.00005236294,0.00001864485],"domain_scores_gemma":[0.9999354,0.00001688108,0.00001679088,0.00001529764,0.000007897486,0.000007775017],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001425687,0.00001579933,0.00004237546,0.00006289789,0.000006658992,0.00006544188,0.00002542332,0.0001114922,0.9956303,0.0006203463,0.0001367353,0.003268363],"study_design_scores_gemma":[0.000002672892,0.00003784415,0.0001831678,0.000001099946,0.000003077707,0.0001171695,0.000003041166,0.0003940383,0.9974802,0.00004233528,0.001732675,0.000002820752],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8493463,0.004029236,0.1262757,0.0005098026,0.0002160096,0.0002843449,0.000555397,0.001373707,0.01740954],"genre_scores_gemma":[0.9444957,0.00181655,0.04162299,0.0001553469,0.00002709982,0.0001157871,0.0003781949,0.00008665906,0.01130151],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001870948,"threshold_uncertainty_score":0.006258965,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008480640921319026,"score_gpt":0.1996742016121804,"score_spread":0.1911935606908613,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}