{"id":"W1968637774","doi":"10.1007/bf03245934","title":"Enantioselective conjugate addition to α,β-unsaturated esters and amides mediated by lithium perchlorate","year":2005,"lang":"en","type":"article","venue":"Journal of the Iranian Chemical Society","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"Queen's University","funders":"","keywords":"Enantioselective synthesis; Conjugate; Chemistry; Lithium perchlorate; Lithium (medication); Organolithium compounds; Diethyl ether; Organic chemistry; Alcohol; Solvent; Lithium amide; Perchlorate; Catalysis; Ion; Deprotonation","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002169719,0.0001765714,0.0002411158,0.00001136485,0.0001255115,0.00007251886,0.0002841605,0.000189076,0.0003503255],"category_scores_gemma":[0.000304351,0.0001261527,0.0002351641,0.0002597472,0.0001261036,0.0002026815,0.00007522707,0.0005444746,0.000006473566],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002610025,"about_ca_system_score_gemma":0.00006438189,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002128319,"about_ca_topic_score_gemma":0.00000106284,"domain_scores_codex":[0.9988762,0.0000208158,0.0004019475,0.0001761616,0.0003056567,0.0002192914],"domain_scores_gemma":[0.9989368,0.0001641589,0.0003115323,0.0001325848,0.000248991,0.0002059796],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006039959,0.00006057649,0.0002337749,0.00003424285,0.0001046984,9.241127e-7,0.000737708,0.00001071823,0.9705521,0.000001886545,0.02710823,0.001094696],"study_design_scores_gemma":[0.0007424061,0.00001390135,0.000228204,0.00008574594,0.00006357526,0.00004540369,0.0004135154,0.0002834092,0.9633778,0.0000493214,0.03452934,0.000167429],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991536,0.0001601233,0.0000480859,0.00763647,0.0000524083,0.00004547249,0.00008561719,0.00002429171,0.0004114854],"genre_scores_gemma":[0.9971351,0.0001056125,0.0005240372,0.001050399,0.0003468205,0.000002170049,0.00002092304,0.00001938787,0.0007955444],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007421113,"threshold_uncertainty_score":0.5144358,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006412499879945096,"score_gpt":0.2140917903725884,"score_spread":0.2076792904926432,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}