{"id":"W1968670540","doi":"10.1016/j.cplett.2011.05.055","title":"Reaction between aminoalkyl radicals and akyl halides: Dehalogenation by electron transfer?","year":2011,"lang":"en","type":"article","venue":"Chemical Physics Letters","topic":"Electron Spin Resonance Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":19,"is_retracted":false,"has_abstract":false,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Chemistry; Iminium; Halide; Radical; Acetonitrile; Electron transfer; Halogenation; Photochemistry; Solvent; Electron paramagnetic resonance; Ion; Reaction rate constant; Inorganic chemistry; Radical ion; Peroxide; Organic chemistry; Kinetics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003882418,0.0002981525,0.0002579656,0.0001695376,0.0002642429,0.0003736335,0.0004915735,0.0009113121,0.004710981],"category_scores_gemma":[0.0002869306,0.000186333,0.0002180796,0.00008570544,0.0003469216,0.0009813986,0.0004290479,0.0005216783,0.0008703048],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000359219,"about_ca_system_score_gemma":0.0001665889,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000413569,"about_ca_topic_score_gemma":0.0002968719,"domain_scores_codex":[0.9998682,0.00002174215,0.000004474678,0.00002834013,0.00001613662,0.00006115097],"domain_scores_gemma":[0.9999166,0.00002281912,0.00001712754,0.00001877788,0.00001377432,0.00001088212],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001359298,0.0001130209,0.0009582989,0.0002651304,0.00005639959,0.001049028,0.000345074,0.0004545918,0.9656019,0.01170842,0.001010515,0.01707822],"study_design_scores_gemma":[0.00004943279,0.0002354073,0.0006014426,0.000008483107,0.00002082198,0.0003804796,0.00008709165,0.001006197,0.9927436,0.001446472,0.003405954,0.0000145949],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.971485,0.001875364,0.01204394,0.00117084,0.0002714823,0.00007467196,0.00009625118,0.0001658502,0.01281665],"genre_scores_gemma":[0.9935641,0.0004245891,0.0008188183,0.0001058053,0.00002073525,0.00001644583,0.00004658774,0.00001446386,0.004988478],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004710981,"threshold_uncertainty_score":0.01575977,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01352129107798286,"score_gpt":0.2294771137938569,"score_spread":0.215955822715874,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}