{"id":"W1968761043","doi":"10.1139/v07-049","title":"Concerted rate-limiting proton transfer to sulfur with nucleophilic attack at phosphorus — A new proposed mechanism for hydrolytic decomposition of the P=S pesticide, Diazinon, in moderately acidic sulfuric acid media","year":2007,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Chemical Institute of Canada","keywords":"Chemistry; Proton; Hydroxide; Hydrolysis; Nucleophile; Sulfuric acid; Aqueous solution; Inorganic chemistry; Decomposition; Hydronium; Catalysis; Organic chemistry; Ion","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004240989,0.0003435224,0.0005350918,0.0001059947,0.0001294357,0.00004725737,0.0005105718,0.0003025213,0.0002912377],"category_scores_gemma":[0.0005942271,0.0002848555,0.0002014153,0.0004285829,0.0001285699,0.0001275783,0.00002181551,0.0005568832,0.000002552307],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001044932,"about_ca_system_score_gemma":0.001987914,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004345192,"about_ca_topic_score_gemma":0.004484346,"domain_scores_codex":[0.9976069,0.00001877221,0.0009245655,0.0003451835,0.0004121106,0.0006924567],"domain_scores_gemma":[0.997532,0.0002433819,0.0002944336,0.0003299931,0.000448588,0.001151676],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008152392,0.00003904839,0.0004139952,0.0002642775,0.00005283667,0.00009995236,0.0006852444,0.0001709678,0.9969432,0.00003272906,0.00005323628,0.0004292633],"study_design_scores_gemma":[0.002628243,0.00007539224,0.0002009362,0.0006775607,0.00008947257,0.0003770419,0.0003580823,0.0002907168,0.9942665,0.0006044863,0.00011953,0.0003120615],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9962179,0.0001029788,0.001875563,0.0006113872,0.00008827176,0.0005259733,0.00004687612,0.0000153875,0.0005156455],"genre_scores_gemma":[0.9988437,0.000006947978,0.0004772892,0.0002166547,0.0001923849,0.00002460737,0.00001901722,0.00007152044,0.0001478279],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004049827,"threshold_uncertainty_score":0.9999604,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01812733092373877,"score_gpt":0.2424393540690489,"score_spread":0.2243120231453102,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}