{"id":"W1968765787","doi":"10.1016/j.molstruc.2005.03.043","title":"(2S,7R,11S,16R)-1,8,10,17-Tetraazapentacyclo[8.8.1.18,17.02,7.011,16]icosane and its enantiomer. Synthesis, NMR analysis and X-ray crystal structure","year":2005,"lang":"en","type":"article","venue":"Journal of Molecular Structure","topic":"Synthesis and Biological Evaluation","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":false,"ca_institutions":"Saint Mary's University","funders":"Dalhousie University","keywords":"Chemistry; Enantiomer; X-ray; Crystallography; Crystal structure; Stereochemistry; Nuclear physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000835639,0.000164603,0.0002144329,0.0001282836,0.0001731054,0.0002124684,0.0002701096,0.000203864,0.008478959],"category_scores_gemma":[0.0001222233,0.0001298789,0.00007227495,0.0001373798,0.0001580068,0.0001810317,0.0001206789,0.0002914392,0.001784873],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000238703,"about_ca_system_score_gemma":0.0002913734,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001211814,"about_ca_topic_score_gemma":0.00236868,"domain_scores_codex":[0.9999393,0.00001173528,0.000003941992,0.00001561117,0.000009223391,0.00002024004],"domain_scores_gemma":[0.999943,0.000006293868,0.00001093561,0.00001010222,0.000008684278,0.00002086495],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001214523,0.0001295719,0.0007152075,0.0002079734,0.0000240038,0.0005355196,0.0001207118,0.001345226,0.9623092,0.003269061,0.002866899,0.0272622],"study_design_scores_gemma":[0.000266594,0.00230992,0.00387268,0.00005028399,0.00004393484,0.002183524,0.0002350628,0.002549076,0.8659956,0.0008218412,0.1216089,0.0000626961],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9417253,0.003143468,0.004955078,0.0003709802,0.000257344,0.0001052151,0.002742059,0.0002617093,0.04643892],"genre_scores_gemma":[0.9596315,0.00142546,0.005655007,0.00013947,0.00002402758,0.00005975409,0.001762002,0.0000543043,0.03124849],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008478959,"threshold_uncertainty_score":0.02836496,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01038933630288595,"score_gpt":0.2515707243428796,"score_spread":0.2411813880399936,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}