{"id":"W1968776443","doi":"10.1002/chem.200400749","title":"An Asymmetric Formal Synthesis of Fasicularin","year":2004,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Trifluoromethanesulfonate; Enol; Natural product; Chemistry; Epoxide; Stereochemistry; Formal synthesis; Thiocyanate; Combinatorial chemistry; Ring (chemistry); Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001394753,0.0005809682,0.0003189368,0.0003718878,0.0003587019,0.0003087402,0.0003406159,0.0002383794,0.004651978],"category_scores_gemma":[0.0001625112,0.0001404316,0.0001932673,0.0003317053,0.0002333522,0.0004698714,0.0006033381,0.0006932886,0.001457253],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003685749,"about_ca_system_score_gemma":0.0006426702,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004692142,"about_ca_topic_score_gemma":0.0008331815,"domain_scores_codex":[0.9998618,0.00001432691,0.00001444867,0.00002769138,0.00003386253,0.00004784769],"domain_scores_gemma":[0.9999377,0.000007653136,0.000009582134,0.000009723828,0.00001227007,0.00002312275],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00016082,0.0002918783,0.0002756628,0.000864153,0.00004268435,0.001351788,0.000386841,0.003301148,0.8850768,0.02168524,0.002404625,0.08415838],"study_design_scores_gemma":[0.000141326,0.001444632,0.001349424,0.00006725208,0.00005005139,0.001322365,0.000130282,0.002009938,0.8673679,0.005079473,0.1209583,0.0000790479],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7573943,0.007619621,0.1275056,0.001089177,0.001455988,0.001126673,0.00347208,0.001394781,0.09894183],"genre_scores_gemma":[0.94669,0.005588763,0.03186016,0.0001885459,0.00009859077,0.0002234252,0.001031444,0.00009068405,0.01422835],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004651978,"threshold_uncertainty_score":0.01556236,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01424204759354144,"score_gpt":0.2482806695027079,"score_spread":0.2340386219091664,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}