{"id":"W1968826288","doi":"10.1039/c3dt53278j","title":"Lactide polymerization catalyzed by Mg and Zn diketiminate complexes with flexible ligand frameworks","year":2014,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"biodegradable polymer synthesis and properties","field":"Materials Science","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"","keywords":"Polymerization; Ligand (biochemistry); Lactide; Chemistry; Catalysis; Alkyl; Substitution (logic); Selectivity; Polymer chemistry; Monomer; Medicinal chemistry; Combinatorial chemistry; Organic chemistry; Polymer; Receptor; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001458146,0.0001718544,0.0002116017,0.00005737189,0.0004616756,0.0001625618,0.0001153091,0.0001294058,0.0003209413],"category_scores_gemma":[0.000007748235,0.0001283063,0.00002865653,0.0001370998,0.0002065724,0.00029528,0.00000551901,0.0001689247,0.0000272534],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001123227,"about_ca_system_score_gemma":0.00002270869,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001024469,"about_ca_topic_score_gemma":0.0001374679,"domain_scores_codex":[0.9990208,0.0000793451,0.0001822116,0.0002975606,0.0001646181,0.0002555069],"domain_scores_gemma":[0.9994581,0.0001036759,0.00007013864,0.0002297663,0.00003001921,0.0001082725],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001145131,0.00007023965,0.0001031398,0.0000494497,0.0000168765,3.217565e-7,0.0005185193,0.00001961636,0.9711915,0.0001768986,0.0001976379,0.0275413],"study_design_scores_gemma":[0.0002650743,0.0000806039,0.0002764253,0.00004837337,0.00005637473,0.00001054994,0.0001289686,0.0007883002,0.9928551,0.00006154252,0.005223358,0.0002053589],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5013903,0.003737152,0.4895914,0.002920669,0.0002661715,0.0001997397,0.0001910002,0.000272708,0.001430853],"genre_scores_gemma":[0.9971207,0.0001351562,0.001442901,0.0002151601,0.00003100254,0.00003487044,0.00002892324,0.00002510019,0.0009661501],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4957304,"threshold_uncertainty_score":0.5232177,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01071563840305985,"score_gpt":0.2136714477708423,"score_spread":0.2029558093677825,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}