{"id":"W1968944434","doi":"10.1139/v08-145","title":"A mechanistic study of the addition of alkynes to Brook silenes","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Alkyne; Silene; Chemistry; Regioselectivity; Trimethylsilyl; Cycloaddition; Propyne; Medicinal chemistry; Stereochemistry; Adduct; Allene; Photochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002901113,0.0005202762,0.0001865723,0.0001683489,0.0002001233,0.0002033368,0.0003560167,0.0003035369,0.00221086],"category_scores_gemma":[0.0003728605,0.0001885274,0.0002290011,0.0001186881,0.0002714658,0.000484175,0.0001924584,0.0004836399,0.0003243477],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004009095,"about_ca_system_score_gemma":0.000253274,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00052731,"about_ca_topic_score_gemma":0.001045893,"domain_scores_codex":[0.9998603,0.00002440947,0.000007047555,0.00003415825,0.00003366442,0.000040436],"domain_scores_gemma":[0.9998245,0.00006721015,0.00004514812,0.00001898476,0.00002425188,0.00002004777],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002491045,0.00008658727,0.0002470679,0.0001533808,0.00001713272,0.0002713692,0.0001234409,0.0006413401,0.9928238,0.001359232,0.00006960728,0.003957778],"study_design_scores_gemma":[0.00001291267,0.0002486989,0.0004841556,0.000004407181,0.000006248605,0.00008536024,0.00001665507,0.0004340883,0.9973583,0.00007760206,0.00126711,0.000004285913],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9850999,0.00102473,0.005472664,0.00009822816,0.00003607019,0.0001414766,0.0001534395,0.00006744951,0.007906091],"genre_scores_gemma":[0.9927344,0.001012173,0.002834386,0.00003244325,0.000007507116,0.00004343255,0.0001003986,0.000007819571,0.003227441],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00221086,"threshold_uncertainty_score":0.007396042,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01679179533870865,"score_gpt":0.1921679391270277,"score_spread":0.1753761437883191,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}