{"id":"W1969150833","doi":"10.1139/v00-023","title":"Silver-catalyzed asymmetric amination of silyl enol ethers","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Enol; Silylation; Amination; Catalysis; Organic chemistry; Silyl enol ether; Adduct; BINAP; Isopropylamine; Toluene; Mesitylene; Medicinal chemistry; Enantioselective synthesis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002802356,0.0001750755,0.0003852484,0.0002363812,0.00007123711,0.00003375641,0.0005042912,0.0002184159,0.008534847],"category_scores_gemma":[0.0004612273,0.0001746715,0.0003003001,0.0007572913,0.0001218417,0.0001283183,0.000007078023,0.000278734,0.00002284384],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002773714,"about_ca_system_score_gemma":0.0007613217,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001174105,"about_ca_topic_score_gemma":0.0001373971,"domain_scores_codex":[0.9985443,0.00001240803,0.0006162766,0.0001645858,0.0003563545,0.0003060864],"domain_scores_gemma":[0.9982728,0.0001419676,0.0004593329,0.0003295732,0.0002390907,0.000557237],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005145972,0.00009803903,0.00554061,0.0002787985,0.0004512166,0.0001676829,0.0005911876,0.0001389938,0.2478068,0.000007634683,0.003339081,0.7415285],"study_design_scores_gemma":[0.0005317318,0.00000982749,0.0006735429,0.0001047473,0.0001338964,0.000133592,0.0006959184,0.00005367708,0.97888,0.00005166496,0.01851234,0.0002190014],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8339014,0.001825862,0.00001410359,0.0001244935,0.00003930558,0.00001654734,0.00004960398,0.000006432279,0.1640223],"genre_scores_gemma":[0.9964792,0.00009168118,0.00008762682,0.00002514427,0.0002195763,0.000001480908,0.00002083747,0.00002537831,0.003049059],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.7413095,"threshold_uncertainty_score":0.9923715,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00676852129922596,"score_gpt":0.1958410287629888,"score_spread":0.1890725074637628,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}