{"id":"W1969228606","doi":"10.1139/v06-123","title":"Triazene derivatives of (1,<i>x</i>)-diazacycloalkanes. Part VII. Synthesis of a series of 1-aryl-2-[3-(3-[2-aryl-1-diazenyl]-1,3-diazepan-1-ylmethyl)-1,3-diazepan-1-yl]-1-diazenes from the reaction of diazonium salts with mixtures of formaldehyde and 1,4-diaminobutane","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Dalhousie University","keywords":"Chemistry; Aryl; Triazene; Molecule; Formaldehyde; Elemental analysis; Medicinal chemistry; Crystallography; Organic chemistry; Alkyl","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004827114,0.0005385421,0.001618951,0.000208212,0.0001064841,0.00002321222,0.0006715047,0.0004735739,0.0003061759],"category_scores_gemma":[0.0008404364,0.0004265872,0.0004864713,0.0005209938,0.00111661,0.0003785853,0.00006577234,0.0005173875,2.563889e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001386731,"about_ca_system_score_gemma":0.001302556,"about_ca_topic_candidate":true,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.01157787,"about_ca_topic_score_gemma":0.002137842,"domain_scores_codex":[0.9962228,0.00004185054,0.002079662,0.0003950367,0.000701262,0.0005594183],"domain_scores_gemma":[0.9932671,0.001339064,0.003222467,0.0007634498,0.0009244006,0.0004834889],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007577577,0.0001978128,0.004712252,0.001070538,0.0005216052,0.00003287491,0.0004772934,0.00005180448,0.9900202,0.00005659324,0.0003730532,0.001728246],"study_design_scores_gemma":[0.001314192,0.0001504925,0.002789693,0.001302699,0.0005650963,0.0002225818,0.002241058,0.00001212963,0.9891254,0.0007396191,0.001171841,0.0003652166],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9923365,0.004116662,0.00003426539,0.0002653454,0.0001207798,0.0001526681,0.001376293,0.00001250708,0.001585046],"genre_scores_gemma":[0.9976635,0.0009198712,0.000792322,0.00001813916,0.0002987663,0.00001718463,0.00007679724,0.00007127363,0.0001421392],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009440032,"threshold_uncertainty_score":0.9998186,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006338219241979501,"score_gpt":0.1812525034889317,"score_spread":0.1749142842469522,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}