{"id":"W1969228606","doi":"10.1139/v06-123","title":"Triazene derivatives of (1,<i>x</i>)-diazacycloalkanes. Part VII. Synthesis of a series of 1-aryl-2-[3-(3-[2-aryl-1-diazenyl]-1,3-diazepan-1-ylmethyl)-1,3-diazepan-1-yl]-1-diazenes from the reaction of diazonium salts with mixtures of formaldehyde and 1,4-diaminobutane","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Dalhousie University","keywords":"Chemistry; Aryl; Triazene; Molecule; Formaldehyde; Elemental analysis; Medicinal chemistry; Crystallography; Organic chemistry; Alkyl","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005148084,0.0003487996,0.0001770852,0.0001964159,0.00009661099,0.0001810718,0.0003193056,0.0002216052,0.003620077],"category_scores_gemma":[0.0001105571,0.0001454366,0.0001866485,0.0001667702,0.0001297112,0.0002140422,0.0001785908,0.0003475631,0.001054244],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002235947,"about_ca_system_score_gemma":0.000146957,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003014728,"about_ca_topic_score_gemma":0.0007056466,"domain_scores_codex":[0.9999443,0.000006937355,0.000005027749,0.0000110818,0.00001207672,0.00002060504],"domain_scores_gemma":[0.9999536,0.000005386661,0.00001659313,0.000004964943,0.000007742513,0.00001167842],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008450602,0.00002422976,0.00007355867,0.0001218657,0.000006552461,0.00008541071,0.00001990013,0.0001520344,0.9948171,0.000412396,0.0001280313,0.004074435],"study_design_scores_gemma":[0.0000311881,0.0006613288,0.001268282,0.00001913472,0.00002395495,0.0003199176,0.00002278159,0.0003791349,0.9837946,0.000123709,0.01334726,0.000008721136],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9567932,0.007483752,0.008478414,0.0002017594,0.0001986744,0.0001144792,0.000902158,0.0003571778,0.0254704],"genre_scores_gemma":[0.9680141,0.006235849,0.007663897,0.0001800982,0.00003436389,0.0001444013,0.0009803694,0.00006332294,0.01668364],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003620077,"threshold_uncertainty_score":0.01211041,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006338219241979501,"score_gpt":0.1812525034889317,"score_spread":0.1749142842469522,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}